{"id":"W2010122581","doi":"10.1021/ic0156285","title":"Carboranes as Ligands for the Preparation of Organometallic Tc and Re Radiopharmaceuticals. Synthesis of [M(CO)<sub>3</sub>(η<sup>5</sup>-2,3-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>)]<sup>-</sup> and <i>r</i><i>ac</i>-[M(CO)<sub>3</sub>(η<sup>5</sup>-2-R-2,3-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>)]<sup>-</sup> (M = Re, <sup>99</sup>Tc; R = CH<sub>2</sub>CH<sub>2</sub>CO<sub>2</sub>H) from [M(CO)<sub>3</sub>Br<sub>3</sub>]<sup>2-</sup>","year":2002,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Boron Compounds in Chemistry","field":"Medicine","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Synthon; Bifunctional; Group 2 organometallic chemistry; Metal; Carborane; Carbonate; Medicinal chemistry; Stereochemistry; Inorganic chemistry; Crystallography; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","sts","open_science","research_integrity","insufficient_payload"],"category_scores_codex":[0.01788777,0.02882688,0.02939214,0.008843577,0.01107977,0.00704535,0.01942142,0.02237801,0.00100118],"category_scores_gemma":[0.01755118,0.03187005,0.01396819,0.02187681,0.0187425,0.01162682,0.01013693,0.02626529,0.005340787],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.01395964,"about_ca_system_score_gemma":0.01233841,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004315814,"about_ca_topic_score_gemma":0.0007704978,"domain_scores_codex":[0.8875954,0.007039566,0.02930529,0.02915419,0.02178149,0.02512408],"domain_scores_gemma":[0.9077684,0.01975589,0.0177838,0.02651169,0.01111923,0.01706101],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01184057,0.01165271,0.002801326,0.01447865,0.01455458,0.003976716,0.01071474,0.01034865,0.8264438,0.0001407798,0.05846811,0.03457939],"study_design_scores_gemma":[0.03653273,0.003988654,0.001243914,0.01009637,0.01926504,0.008382445,0.008943283,0.03320075,0.8461159,0.001562086,0.005695732,0.02497303],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9156128,0.02402616,0.001056962,0.004717512,0.003251436,0.02300251,0.01786537,0.008273547,0.002193764],"genre_scores_gemma":[0.8844381,0.06071117,0.0007285274,0.005395372,0.01458331,0.009099331,0.01474328,0.01010135,0.0001995769],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05277237,"threshold_uncertainty_score":0.999912,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01996247199763169,"score_gpt":0.2653120729770347,"score_spread":0.245349600979403,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}