{"id":"W2010122581","doi":"10.1021/ic0156285","title":"Carboranes as Ligands for the Preparation of Organometallic Tc and Re Radiopharmaceuticals. Synthesis of [M(CO)<sub>3</sub>(η<sup>5</sup>-2,3-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>)]<sup>-</sup> and <i>r</i><i>ac</i>-[M(CO)<sub>3</sub>(η<sup>5</sup>-2-R-2,3-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>)]<sup>-</sup> (M = Re, <sup>99</sup>Tc; R = CH<sub>2</sub>CH<sub>2</sub>CO<sub>2</sub>H) from [M(CO)<sub>3</sub>Br<sub>3</sub>]<sup>2-</sup>","year":2002,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Boron Compounds in Chemistry","field":"Medicine","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Synthon; Bifunctional; Group 2 organometallic chemistry; Metal; Carborane; Carbonate; Medicinal chemistry; Stereochemistry; Inorganic chemistry; Crystallography; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001721833,0.0003235984,0.0002316551,0.0001983143,0.0001845022,0.0003630245,0.0006402172,0.0004858729,0.002648252],"category_scores_gemma":[0.00031623,0.0002157457,0.0001434793,0.0002454514,0.0002396231,0.0003541928,0.0004887571,0.0007420672,0.0009868146],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000575283,"about_ca_system_score_gemma":0.0003465237,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001088308,"about_ca_topic_score_gemma":0.002395519,"domain_scores_codex":[0.9998253,0.00002746985,0.00001343157,0.00004312021,0.00005799648,0.00003263951],"domain_scores_gemma":[0.9999261,0.00001278102,0.0000203473,0.0000130179,0.00001202756,0.00001569172],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002280563,0.00004629032,0.0001851604,0.0005680481,0.00002771576,0.000144173,0.0001196974,0.0004698802,0.9738807,0.005568037,0.001621,0.01714124],"study_design_scores_gemma":[0.00004924293,0.0001390836,0.0003301565,0.0000278488,0.00001893595,0.0004439313,0.0000385319,0.0009995382,0.9614433,0.000398407,0.03609177,0.00001931108],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7436091,0.03476277,0.147864,0.001111586,0.0006497413,0.0008290207,0.002044772,0.002927924,0.06620109],"genre_scores_gemma":[0.9367933,0.005462443,0.043035,0.0002483108,0.00004792745,0.0002468648,0.0008784056,0.0001783486,0.01310952],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002648252,"threshold_uncertainty_score":0.008859336,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01996247199763169,"score_gpt":0.2653120729770347,"score_spread":0.245349600979403,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}