{"id":"W2010128918","doi":"10.1002/jrs.2151","title":"Vibrational spectroscopic study of the hydrated platinum(II), palladium(II) and <i>cis</i>‐diammineplatinum(II) ions in acidic aqueous solutions","year":2008,"lang":"en","type":"article","venue":"Journal of Raman Spectroscopy","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; National Research Foundation; University of Calgary","keywords":"Chemistry; Palladium; Aqueous solution; Platinum; Raman spectroscopy; Ion; Molecule; Ligand (biochemistry); Infrared spectroscopy; Density functional theory; Crystallography; Inorganic chemistry; Analytical Chemistry (journal); Physical chemistry; Computational chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001938958,0.0002725711,0.0001976211,0.0001440906,0.0001203409,0.0002354355,0.0003419999,0.0002603423,0.0007418752],"category_scores_gemma":[0.000336201,0.0001519775,0.0001084857,0.0001582641,0.0002583604,0.0001824037,0.0001850418,0.0003478901,0.0001644424],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001227826,"about_ca_system_score_gemma":0.00009567412,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004310885,"about_ca_topic_score_gemma":0.000299722,"domain_scores_codex":[0.9998635,0.00002394999,0.000008621263,0.00002927557,0.00005774108,0.0000169535],"domain_scores_gemma":[0.999908,0.00002620638,0.00001964539,0.000005316609,0.00002449907,0.00001628206],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004768002,0.000007589855,0.000120932,0.00004373315,0.000005608531,0.00002441547,0.00003484026,0.0002493546,0.9985183,0.0000477684,0.00002153068,0.0008781677],"study_design_scores_gemma":[0.00002042666,0.0003393448,0.002094863,0.00000975162,0.00001694931,0.0000960544,0.0001167259,0.003474442,0.9927663,0.00005798523,0.0009959257,0.0000112276],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956816,0.0006144435,0.002464592,0.00005513946,0.0000160821,0.00001408113,0.00008288417,0.00003460419,0.001036737],"genre_scores_gemma":[0.9962077,0.0005030542,0.002330236,0.00003940879,0.000007375881,0.00001959738,0.00014706,0.000009234468,0.0007363143],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007418752,"threshold_uncertainty_score":0.002481818,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01213870315915259,"score_gpt":0.2368653648470383,"score_spread":0.2247266616878857,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}