{"id":"W2010208140","doi":"10.1021/ac300844d","title":"Protocol for an Electrospray Ionization Tandem Mass Spectral Product Ion Library: Development and Application for Identification of 240 Pesticides in Foods","year":2012,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Pesticide Residue Analysis and Safety","field":"Agricultural and Biological Sciences","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"Sciex (Canada); Ministry of the Environment, Conservation and Parks","funders":"","keywords":"Chemistry; Chromatography; Electrospray ionization; Quechers; Mass spectrometry; Carbendazim; Tandem mass spectrometry; Pesticide; Pesticide residue; Azoxystrobin; Selected reaction monitoring; Fungicide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002743365,0.002773764,0.0015372,0.003000649,0.002038309,0.001222275,0.002534481,0.001546316,0.03136527],"category_scores_gemma":[0.002996315,0.001965289,0.001194839,0.002233109,0.0008405417,0.001271217,0.001689452,0.002761005,0.02632885],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007255977,"about_ca_system_score_gemma":0.002484688,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008507773,"about_ca_topic_score_gemma":0.002016769,"domain_scores_codex":[0.9971365,0.0005520352,0.0003370146,0.0007314823,0.0009686348,0.0002744196],"domain_scores_gemma":[0.9980108,0.0002894592,0.0001310655,0.0004107255,0.0009901085,0.0001678599],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001149261,0.0004891185,0.0005948469,0.001401079,0.0001390421,0.000887324,0.000278917,0.0008206668,0.9204753,0.002207496,0.0312017,0.04035519],"study_design_scores_gemma":[0.0009080073,0.002682434,0.006053102,0.0003905127,0.0001976445,0.003545356,0.0001732187,0.004317942,0.5632339,0.002432166,0.4156643,0.0004014206],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"protocol","genre_scores_codex":[0.03479713,0.003100049,0.8270525,0.0009540545,0.0006511931,0.06527077,0.03578428,0.01295286,0.01943701],"genre_scores_gemma":[0.04355703,0.003955642,0.6768368,0.002056146,0.0002727658,0.1423279,0.09778084,0.002471754,0.03074131],"genre_candidate":"protocol","genre_consensus":null,"teacher_disagreement_score":0.03136527,"threshold_uncertainty_score":0.1049273,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02637615441964694,"score_gpt":0.2875495669403826,"score_spread":0.2611734125207357,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}