{"id":"W2010382956","doi":"10.1139/v06-035","title":"Towards C-2 symmetrical macrocyles with an incorporated sucrose unit","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Ruthenium; Metathesis; Regioselectivity; Ring-closing metathesis; HEXA; Yield (engineering); Stereochemistry; Grubbs' catalyst; Salt metathesis reaction; Catalysis; Combinatorial chemistry; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001725252,0.0002984491,0.0004023458,0.00009979835,0.0001601796,0.0001695966,0.0005566775,0.0003046076,0.002586514],"category_scores_gemma":[0.0001287706,0.0002681284,0.000141246,0.0004744962,0.000278235,0.0002010284,0.00001436303,0.000544089,0.000005748093],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002957592,"about_ca_system_score_gemma":0.002364208,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00358875,"about_ca_topic_score_gemma":0.002061153,"domain_scores_codex":[0.9983581,0.00001424825,0.0005445148,0.0002532316,0.0003296262,0.0005002643],"domain_scores_gemma":[0.9975801,0.00005574368,0.0003992199,0.0003860972,0.0004514175,0.001127492],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001823822,0.0001205355,0.01457103,0.0002532649,0.0001190262,0.003522536,0.00008654995,0.0001988385,0.9772069,0.00003401371,0.001586633,0.002118222],"study_design_scores_gemma":[0.0007214992,0.00002782155,0.0005132287,0.0001334847,0.00006832921,0.001944752,0.0004538827,0.00004590986,0.9855366,0.0003072252,0.009857411,0.0003898407],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9243308,0.0003347552,0.00002411537,0.0001835953,0.0000354469,0.00001629805,0.0001047046,0.00002353569,0.07494676],"genre_scores_gemma":[0.9964564,0.00000598934,0.0003921333,0.00003969526,0.0006648114,0.000002319915,0.00008827413,0.00004533162,0.002304971],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07264179,"threshold_uncertainty_score":0.9999771,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01231278691463549,"score_gpt":0.2020710706509929,"score_spread":0.1897582837363574,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}