{"id":"W2010787206","doi":"10.1021/ic048926l","title":"Reaction of Thiols with N-Bonded Sulfenamide Complexes of Cobalt(III):  Steric Effect and Reaction Pathway","year":2004,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Sulfenamide; Steric effects; Cobalt; Organic chemistry; Stereochemistry; Computational chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002046911,0.000287409,0.0004971889,0.00003829646,0.00005221567,0.00001504829,0.0001987076,0.0002718239,0.00008713883],"category_scores_gemma":[0.0001408528,0.000262181,0.00007850687,0.0002019837,0.0002212867,0.0001196623,0.0000607278,0.0002768041,0.000002021734],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002340159,"about_ca_system_score_gemma":0.0001376179,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003795512,"about_ca_topic_score_gemma":0.00002083662,"domain_scores_codex":[0.9985615,0.00002111754,0.0004632991,0.0003944511,0.0003290132,0.0002306428],"domain_scores_gemma":[0.9984774,0.0002229422,0.0004988472,0.0005969547,0.0001179873,0.00008585793],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002989063,0.0001297912,0.001758314,0.0009558647,0.00007039874,0.000008713051,0.0001164287,7.220746e-7,0.995554,0.00001439071,0.00001589733,0.001076606],"study_design_scores_gemma":[0.001357298,0.00009324933,0.00147309,0.0005088295,0.00007739689,0.000146025,0.0002135703,0.000002205557,0.9956197,0.0001815812,0.0000793899,0.00024765],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941319,0.0001233791,0.00004233125,0.0000298816,0.00001589836,0.0001265253,0.00003430909,0.0002183378,0.005277432],"genre_scores_gemma":[0.9993436,0.00003775577,0.0003258366,0.000009778202,0.00005847436,0.0000250534,0.00005034637,0.00004808647,0.0001010239],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005211739,"threshold_uncertainty_score":0.999983,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006780185399652903,"score_gpt":0.2164671696457587,"score_spread":0.2096869842461058,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}