{"id":"W2010953317","doi":"10.1007/s00723-014-0516-8","title":"Orientation Information from the Dipolar Interaction Between a Complex in the Excited Quartet State and a Doublet Spin Label","year":2014,"lang":"en","type":"article","venue":"Applied Magnetic Resonance","topic":"Electron Spin Resonance Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"Brock University","funders":"","keywords":"Multiplet; Excited state; Polarization (electrochemistry); Chemistry; Dipole; Excitation; Orientation (vector space); Intersystem crossing; Atomic physics; Spin polarization; Principal axis theorem; Physics; Electron; Quantum mechanics; Singlet state; Spectral line; Geometry; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002413856,0.0002117791,0.0002263612,0.0003566557,0.0003159961,0.0006398039,0.0002752825,0.000356612,0.005164668],"category_scores_gemma":[0.0005920254,0.0002289568,0.0001019728,0.0004168093,0.0002256019,0.0005180511,0.0002333209,0.0006546567,0.0005733365],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003938222,"about_ca_system_score_gemma":0.0002780397,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005054192,"about_ca_topic_score_gemma":0.001350584,"domain_scores_codex":[0.9999033,0.00001046108,0.000004776402,0.00002781626,0.00003240822,0.00002120578],"domain_scores_gemma":[0.9996131,0.0001084046,0.00008737582,0.00006700927,0.00005310839,0.00007106944],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002663504,0.00001958829,0.0008225419,0.00004453373,0.000005318182,0.00006403715,0.00002391452,0.0001431611,0.992231,0.00141327,0.0001648048,0.004801529],"study_design_scores_gemma":[0.00003440613,0.0001225261,0.006590407,0.00000888689,0.00004045579,0.0002502521,0.00006087195,0.003188177,0.9855359,0.001192111,0.002949394,0.00002676848],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9604356,0.0003289302,0.02734667,0.0003575157,0.0001016467,0.00001590363,0.000736796,0.0001415069,0.01053537],"genre_scores_gemma":[0.989678,0.00027005,0.006057544,0.0001161201,0.00002026556,0.000008575291,0.000817958,0.00006313867,0.002968351],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005164668,"threshold_uncertainty_score":0.01727748,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01159988964336357,"score_gpt":0.2595048235677918,"score_spread":0.2479049339244282,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}