{"id":"W2011099977","doi":"10.1021/ic4022195","title":"Synthesis of (TDAE)(O<sub>2</sub>SSO<sub>2</sub>)(s) and Discovery of (TDAE)(O<sub>2</sub>SSSSO<sub>2</sub>)(s) Containing the First Polythionite, [O<sub>2</sub>SSSSO<sub>2</sub>]<sup>2–</sup>","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Crandall University; University of New Brunswick","funders":"","keywords":"Chemistry; Raman spectroscopy; Antibonding molecular orbital; Crystallography; Diradical; Dissociation (chemistry); Unpaired electron; Tetrathiafulvalene; Chalcogen; Electron; Molecule; Physical chemistry; Atomic orbital; Singlet state; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006324482,0.0002785707,0.0001284909,0.0001279083,0.0001296133,0.0001731242,0.0001317448,0.0002691469,0.001563306],"category_scores_gemma":[0.0001270285,0.0001641448,0.000181206,0.0001904102,0.0001136675,0.0002449756,0.0002162257,0.0002522735,0.0005439428],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001456431,"about_ca_system_score_gemma":0.0002078534,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003987255,"about_ca_topic_score_gemma":0.001423726,"domain_scores_codex":[0.9999527,0.000003190612,0.000004372735,0.00001339106,0.00001775183,0.000008570834],"domain_scores_gemma":[0.9999444,0.000005923165,0.00001487861,0.000006336837,0.00001567708,0.00001266403],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001938122,0.000007751595,0.00009796192,0.00006065737,0.000004155909,0.00005069515,0.00001442233,0.0001019733,0.9964516,0.0002453643,0.00007135287,0.002874698],"study_design_scores_gemma":[0.000008695254,0.0002311886,0.001566274,0.000005509636,0.00000907728,0.0002524757,0.00002334145,0.0006463709,0.9880779,0.00009254166,0.009078606,0.000007970589],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9708426,0.001526615,0.01898918,0.0001198014,0.0001006388,0.0001346815,0.0007093673,0.0002418597,0.007335302],"genre_scores_gemma":[0.9590468,0.001739182,0.02595563,0.00008181409,0.00002539297,0.0001119551,0.00103006,0.00008775287,0.01192133],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001563306,"threshold_uncertainty_score":0.005229771,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005568898076096558,"score_gpt":0.1938675142275878,"score_spread":0.1882986161514912,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}