{"id":"W2011285625","doi":"10.1021/ja0775063","title":"Palladium-Catalyzed Methylation of Aryl C−H Bond by Using Peroxides","year":2008,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":242,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Catalysis; Hydrogen peroxide; Palladium; Acetanilide; Aryl; Reagent; Methylation; Peroxide; Hydrogen bond; Acceptor; Medicinal chemistry; Photochemistry; Organic chemistry; Combinatorial chemistry; Molecule; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001797049,0.000561642,0.0002565946,0.0001271387,0.0001171866,0.0001775404,0.0003445871,0.0002778738,0.0007092864],"category_scores_gemma":[0.0001890219,0.0002324252,0.0002020745,0.0001183929,0.000213881,0.0003753906,0.0003785619,0.0005485127,0.0002388728],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002222258,"about_ca_system_score_gemma":0.0001955141,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003452787,"about_ca_topic_score_gemma":0.00043936,"domain_scores_codex":[0.9999032,0.00001134322,0.000007522767,0.00003025209,0.00001875515,0.00002898028],"domain_scores_gemma":[0.9999615,0.000005913982,0.00001061506,0.000007222814,0.00000615648,0.000008577345],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001396465,0.00002990454,0.0002030034,0.0001818583,0.00001362506,0.0003113456,0.00005445909,0.0002432331,0.9899204,0.0008650351,0.0001804682,0.007857095],"study_design_scores_gemma":[0.00002327768,0.0001344547,0.0002751099,0.000002639111,0.00001061949,0.0001938651,0.000007878007,0.0004190221,0.9962674,0.0001012093,0.002558584,0.000006007079],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9682321,0.004641126,0.01962885,0.0002624913,0.0001080941,0.0001026395,0.0002033043,0.0002967566,0.006524608],"genre_scores_gemma":[0.991809,0.001559641,0.004213377,0.00003452987,0.00001346108,0.00002525999,0.0001187325,0.00001514564,0.002210961],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007092864,"threshold_uncertainty_score":0.002372801,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02706810279256896,"score_gpt":0.2913627922821375,"score_spread":0.2642946894895685,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}