{"id":"W2011723548","doi":"10.1021/ol040016k","title":"Bilirubin as an Antioxidant:  Kinetic Studies of the Reaction of Bilirubin with Peroxyl Radicals in Solution, Micelles, and Lipid Bilayers","year":2004,"lang":"en","type":"article","venue":"Organic Letters","topic":"Heme Oxygenase-1 and Carbon Monoxide","field":"Biochemistry, Genetics and Molecular Biology","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"Mount Allison University","funders":"","keywords":"Chemistry; Trolox; Micelle; Antioxidant; Photochemistry; Chlorobenzene; Radical; Cumene hydroperoxide; Bilirubin; Cumene; Organic chemistry; Aqueous solution; Catalysis; Antioxidant capacity","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001212821,0.000602545,0.0007982034,0.0002918878,0.0002526334,0.0006482216,0.0004736971,0.0005816824,0.0007737797],"category_scores_gemma":[0.001217836,0.0003037801,0.0002922038,0.0003885364,0.0003720082,0.0009566967,0.0003739999,0.0009085771,0.0005787199],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005071397,"about_ca_system_score_gemma":0.000303407,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009666405,"about_ca_topic_score_gemma":0.0006187449,"domain_scores_codex":[0.9995103,0.0001614446,0.00002807785,0.00007206922,0.0001324901,0.00009562857],"domain_scores_gemma":[0.9994515,0.00016205,0.00008823063,0.0000435956,0.0001664689,0.0000881947],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005826248,0.00007858223,0.0008905013,0.0002699162,0.00005157816,0.00006229588,0.0001504991,0.0004727685,0.990837,0.0006309932,0.0001255697,0.005847635],"study_design_scores_gemma":[0.00003212223,0.0003551924,0.001697856,0.00002081492,0.00003492582,0.0002294942,0.00004871242,0.005238691,0.989744,0.0001626923,0.0024168,0.00001868803],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.959032,0.01659877,0.02065895,0.0002469314,0.00008895999,0.0001344371,0.000237668,0.000175288,0.002826895],"genre_scores_gemma":[0.9856033,0.004327722,0.006069007,0.00005155621,0.00002152436,0.0000457781,0.0003614085,0.00005864082,0.003461063],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001212821,"threshold_uncertainty_score":0.006414056,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00858944793691585,"score_gpt":0.2300116767663867,"score_spread":0.2214222288294709,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}