{"id":"W2011882762","doi":"10.1016/j.carres.2009.08.028","title":"One-pot synthesis of highly functionalized morphans from C-glycosides","year":2009,"lang":"en","type":"article","venue":"Carbohydrate Research","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"Institute for Biological Sciences; National Research Council Canada","funders":"","keywords":"Chemistry; Iminium; Stereocenter; Michael reaction; Sodium cyanoborohydride; Cascade reaction; Nitroalkene; Intramolecular force; Amine gas treating; Thiolactone; Reagent; Tandem; Combinatorial chemistry; Stereochemistry; Organic chemistry; Catalysis; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001554546,0.0004630951,0.0001999044,0.0002293741,0.0002198435,0.0001705612,0.0003130241,0.0002372296,0.001536085],"category_scores_gemma":[0.0001255808,0.000147881,0.0001836711,0.0002558039,0.000197685,0.0004240304,0.0004292113,0.0005424374,0.0004269856],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003527894,"about_ca_system_score_gemma":0.0003220378,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000405627,"about_ca_topic_score_gemma":0.0008804367,"domain_scores_codex":[0.9999187,0.000009546473,0.000006074592,0.00001183103,0.00001880856,0.00003503335],"domain_scores_gemma":[0.9999452,0.000009551569,0.00001361836,0.000007436046,0.000006527384,0.00001774486],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001620811,0.00008706541,0.0001809713,0.0002042159,0.00001840901,0.000503619,0.0001514323,0.001126551,0.9763465,0.004304362,0.0005318044,0.01638294],"study_design_scores_gemma":[0.00002514948,0.0002239331,0.0008549874,0.00001033284,0.00001215813,0.0002581107,0.00002140508,0.0007294834,0.990014,0.0005370915,0.007297833,0.0000155497],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.957536,0.001870028,0.02294733,0.0002899867,0.0001369983,0.0001493643,0.000684684,0.000208763,0.01617691],"genre_scores_gemma":[0.9832692,0.00164715,0.009973023,0.00008379234,0.00002237212,0.00005520212,0.0002428018,0.00004256566,0.004663896],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001536085,"threshold_uncertainty_score":0.005138695,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06675113397871976,"score_gpt":0.3120399621545812,"score_spread":0.2452888281758614,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}