{"id":"W2011961212","doi":"10.1002/ejoc.200400328","title":"Synthesis of New Tetrazole‐Substituted Pyroaminoadipic and Pipecolic Acid Derivatives","year":2005,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Synthesis of Tetrazole Derivatives","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Centre National de la Recherche Scientifique; Agence Universitaire de la Francophonie","keywords":"Chemistry; Tetrazole; Amide; Sodium azide; Hydrolysis; Azide; Transfer hydrogenation; Aryl; Pipecolic acid; Alkylation; Organic chemistry; Catalysis; Amino acid; Alkyl","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003986861,0.0003437901,0.0005697044,0.00008091925,0.00007502872,0.00005349289,0.0007534237,0.00008256278,0.004346611],"category_scores_gemma":[0.00171316,0.000327746,0.00018221,0.0002021852,0.0002640844,0.0003044765,0.000148225,0.0004406951,0.00002611847],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009495158,"about_ca_system_score_gemma":0.0001815731,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":9.479482e-7,"about_ca_topic_score_gemma":6.376331e-7,"domain_scores_codex":[0.9979373,0.00005737164,0.001005892,0.000285628,0.0004006044,0.0003132614],"domain_scores_gemma":[0.9977851,0.0002782628,0.0009980132,0.0004295438,0.0001658906,0.0003432003],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005887168,0.0001204453,0.001456147,0.000183974,0.000233987,0.0000726434,0.0006803984,0.000004588738,0.9599092,0.000002569039,0.0006034747,0.03667372],"study_design_scores_gemma":[0.0008643795,0.00001684779,0.008736241,0.0004033623,0.0001179809,0.0004965339,0.0006356977,0.000007555807,0.9829305,0.00001177387,0.005484197,0.000294915],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9785025,0.002267616,0.0001587834,0.0004848589,0.00004404043,0.00002645627,0.00001043951,0.00004612377,0.01845923],"genre_scores_gemma":[0.995065,0.0003293472,0.0030774,0.00003527548,0.000791328,5.217594e-7,0.000001873712,0.00008290686,0.000616371],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03637881,"threshold_uncertainty_score":0.9999174,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01249418779996062,"score_gpt":0.2122144528803797,"score_spread":0.199720265080419,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}