{"id":"W2012140640","doi":"10.1021/jo8010705","title":"Nucleophilic Addition of Phenol Derivatives to Methyl 1-Nitrocyclopropanecarboxylates","year":2008,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":114,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Nucleophile; Cyclopropane; Phenol; Chemistry; Alcohol; Enantioselective synthesis; Enantiomer; Ring (chemistry); Organic chemistry; Medicinal chemistry; Atomoxetine; Catalysis; Medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002138941,0.0002204716,0.0003872713,0.00004624113,0.0001344278,0.000008832872,0.0005688727,0.000126687,0.005558505],"category_scores_gemma":[0.0003671497,0.0001652392,0.0001530285,0.0002855424,0.0001217988,0.0001135871,0.0001039262,0.0004743849,0.00002585953],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001812928,"about_ca_system_score_gemma":0.0001784857,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005872749,"about_ca_topic_score_gemma":6.879411e-7,"domain_scores_codex":[0.9984171,0.00002878602,0.000657188,0.0001460081,0.0005211862,0.0002297351],"domain_scores_gemma":[0.9980974,0.0001852569,0.0007582894,0.0004201309,0.0003820155,0.0001569174],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001485775,0.00007975293,0.00005581197,0.0001350368,0.0001013309,0.00001895812,0.002175624,0.00001761995,0.9960302,0.000002593943,0.0002095864,0.001024979],"study_design_scores_gemma":[0.0005267704,0.0000501351,0.0001591557,0.0001093809,0.00009944867,0.00174652,0.002863668,0.000004529295,0.9928088,0.0001814426,0.001284112,0.0001660427],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948528,0.0004905801,0.0002894988,0.0002246859,0.00006409462,0.00005302668,0.00001322196,0.00003403919,0.003977982],"genre_scores_gemma":[0.9978979,0.0002991292,0.0008936151,0.00003812545,0.0004072348,0.000002102791,0.000005657465,0.00004744041,0.0004088209],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005532645,"threshold_uncertainty_score":0.9953505,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01339203629594964,"score_gpt":0.2160353772272657,"score_spread":0.202643340931316,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}