{"id":"W2012183668","doi":"10.1021/om0008631","title":"A Density Functional Study of the Competing Processes Occurring in Solution during Ethylene Polymerization by the Catalyst (1,2-Me<sub>2</sub>Cp)<sub>2</sub>ZrMe<sup>+</sup>","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Polymerization; Ethylene; Catalysis; Alkyl; Olefin fiber; Chain termination; Polymer chemistry; Medicinal chemistry; Crystallography; Stereochemistry; Radical polymerization; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005771912,0.0005423253,0.0006780314,0.0002363587,0.0008082536,0.0001448054,0.0007892936,0.0001917294,0.0004746191],"category_scores_gemma":[0.000504288,0.00042404,0.0002523431,0.002593215,0.0002230508,0.0003571701,0.0005764264,0.0005300043,0.00002799198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003164283,"about_ca_system_score_gemma":0.0001874778,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001748009,"about_ca_topic_score_gemma":0.0006591461,"domain_scores_codex":[0.9962507,0.0001860424,0.001063815,0.0008435458,0.0009900236,0.0006658451],"domain_scores_gemma":[0.9975912,0.0003031987,0.0006843102,0.001040897,0.0002508883,0.0001295049],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007387808,0.001088663,0.04458218,0.0002350084,0.0002707572,0.000006429092,0.001730673,0.000839092,0.9480895,0.00001089026,0.000008724725,0.003064204],"study_design_scores_gemma":[0.001022783,0.00003697658,0.02585287,0.0001193318,0.000357442,0.00005677422,0.005162359,0.001185009,0.9655266,0.00001841367,0.0001561717,0.0005052817],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980048,0.0006141805,0.0002690901,0.0001809989,0.00008775494,0.0003967141,0.00005741634,0.0001094209,0.0002796258],"genre_scores_gemma":[0.9991286,0.0001798241,0.0000103388,0.0000530217,0.0002013234,0.00007786763,0.0001547359,0.00009181471,0.0001024866],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0187293,"threshold_uncertainty_score":0.9998211,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01201334466780104,"score_gpt":0.1992985809737602,"score_spread":0.1872852363059591,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}