{"id":"W2012250634","doi":"10.1016/s0960-894x(02)00104-x","title":"Stereoselective synthesis of a C-glycoside analogue of N-Fmoc-serine β-N-acetylglucosaminide by ramberg–bäcklund rearrangement","year":2002,"lang":"en","type":"article","venue":"Bioorganic & Medicinal Chemistry Letters","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"National Center for Research Resources; National Institute of General Medical Sciences; National Institutes of Health; Canadian Bee Research Fund","keywords":"Chemistry; Stereoselectivity; Stereochemistry; Glycoside; Serine; Thio-; Derivative (finance); Sulfone; Chemical synthesis; Organic chemistry; Biochemistry; Enzyme; In vitro","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002729738,0.0005639226,0.0009776335,0.0000582476,0.00008380882,0.00001805215,0.0006649864,0.0003050109,0.01155786],"category_scores_gemma":[0.0005898107,0.0005645354,0.0003046835,0.0004644865,0.000535934,0.00009405528,0.0001309354,0.0004159304,0.00002079317],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002814383,"about_ca_system_score_gemma":0.00005280554,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001642285,"about_ca_topic_score_gemma":0.000004921968,"domain_scores_codex":[0.996758,0.00004186677,0.001045371,0.0007400964,0.0007875188,0.0006271007],"domain_scores_gemma":[0.9974966,0.0004665186,0.0006638155,0.0009296935,0.0001423211,0.0003010272],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001544161,0.0003114977,0.0005895999,0.001314658,0.0004289072,0.00005506442,0.0002721867,0.000001836779,0.9824221,0.000001112963,0.01274575,0.001702824],"study_design_scores_gemma":[0.0009061426,0.00002528591,0.00008267918,0.0004670729,0.0003523631,0.00008903671,0.0006417949,0.00006606823,0.9939423,0.00000458979,0.002944626,0.0004779921],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9855,0.001033675,0.00004932699,0.001754465,0.00006128498,0.0001026293,0.0002947559,0.00008725782,0.01111658],"genre_scores_gemma":[0.9979547,0.0003308677,0.0001457384,0.0001689643,0.000301529,0.00004584824,0.00009453871,0.00007541117,0.000882406],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01245467,"threshold_uncertainty_score":0.9996806,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01047474883268163,"score_gpt":0.1888470397209446,"score_spread":0.178372290888263,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}