{"id":"W2012281486","doi":"10.1021/ma001852m","title":"In-Situ Thermoreversible Gelation of Block and Star Copolymers of Poly(ethylene glycol) and Poly(<i>N</i>-isopropylacrylamide) of Varying Architectures","year":2001,"lang":"en","type":"article","venue":"Macromolecules","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":232,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Ethylene glycol; Syneresis; Copolymer; Polymer; Polymer chemistry; Lower critical solution temperature; Materials science; Poly(N-isopropylacrylamide); Chemical engineering; Chemistry; Composite material; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001342873,0.000291507,0.0001136989,0.00007982222,0.0000552006,0.0001064145,0.0001051467,0.0001273495,0.0003769547],"category_scores_gemma":[0.0001051317,0.0001169075,0.000150944,0.00004437648,0.00009897702,0.0001913154,0.0001038074,0.000246189,0.00008841532],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009396625,"about_ca_system_score_gemma":0.0001028626,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002105779,"about_ca_topic_score_gemma":0.0003070309,"domain_scores_codex":[0.9999422,0.00001002871,0.000003562047,0.00001493921,0.00001300343,0.00001627875],"domain_scores_gemma":[0.9999187,0.00001346037,0.00004099155,0.000004879359,0.000007143666,0.00001479063],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002422472,0.000005483762,0.00002304663,0.00001413513,0.000001504756,0.000009027332,0.000006133333,0.00003222399,0.9993097,0.00002552913,0.000005477333,0.0005435688],"study_design_scores_gemma":[0.000004105747,0.000117523,0.0002723502,0.00000121253,0.000003971343,0.00003003787,0.000002126445,0.0004552458,0.9987601,0.00000883672,0.0003431511,0.000001456613],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952807,0.0006830629,0.003268686,0.00002723588,0.00001282527,0.00001229584,0.00003317287,0.00005013642,0.0006319089],"genre_scores_gemma":[0.9936551,0.0003822883,0.004710767,0.00002261056,0.000006515022,0.00001733485,0.0000459739,0.00001996306,0.001139476],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0003769547,"threshold_uncertainty_score":0.001261115,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008892614861491557,"score_gpt":0.2268118675617854,"score_spread":0.2179192527002938,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}