{"id":"W2012320121","doi":"10.1021/om020641y","title":"Diplatinum-Center-Mediated Transformation of a Substituted Benzene to a Cyclohexadienyl Dianion and the Breaking of C−Cl Bonds:  Syntheses and Structures of Pt<sub>2</sub>R<sub>4</sub>(ttab) and Pt<sub>2</sub>(CH<sub>3</sub>)<sub>4</sub>(ttab)Cl<sub>2</sub>","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Benzene; Ring (chemistry); Platinum; Ligand (biochemistry); van der Waals force; Medicinal chemistry; Molecule; Yield (engineering); Center (category theory); Crystallography; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005507047,0.0002427081,0.0001345506,0.00008359092,0.0001156014,0.0001589678,0.0002023689,0.0001559593,0.001998101],"category_scores_gemma":[0.00008675846,0.0001191758,0.0001085653,0.0001300536,0.0001324991,0.0001516777,0.0002485204,0.0002556954,0.0003925133],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003919018,"about_ca_system_score_gemma":0.0002997495,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001056435,"about_ca_topic_score_gemma":0.002800554,"domain_scores_codex":[0.9999394,0.000005983071,0.000004102676,0.00001412913,0.00001087506,0.0000256006],"domain_scores_gemma":[0.9999615,0.000003121961,0.00001216433,0.000006301731,0.000004682656,0.00001231099],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008039224,0.00002967988,0.0001302346,0.00007464914,0.000007035075,0.00007917389,0.00005234601,0.0002383123,0.9959521,0.0005681643,0.0000825333,0.002705409],"study_design_scores_gemma":[0.00001288258,0.0001482419,0.0006587298,0.000002221871,0.000005777585,0.00007677565,0.00001377084,0.0003142321,0.995594,0.00003026727,0.003138651,0.000004316314],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.986637,0.0007948558,0.005492776,0.00006895827,0.00004591219,0.00005973831,0.0002316569,0.0001238212,0.00654534],"genre_scores_gemma":[0.9940357,0.0003715601,0.001918733,0.0000218187,0.000002348482,0.00001796026,0.000141649,0.00001684095,0.003473473],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001998101,"threshold_uncertainty_score":0.006684303,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01108740885715032,"score_gpt":0.2023311109304765,"score_spread":0.1912437020733262,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}