{"id":"W2012467283","doi":"10.1002/cjoc.201090137","title":"Kinetics and Mechanism Investigation of the Reaction between Triphenylphosphine, Di‐<i>tert</i>‐butyl Acetylenedicarboxilate and OH‐Acid","year":2010,"lang":"en","type":"article","venue":"Chinese Journal of Chemistry","topic":"Phosphorus compounds and reactions","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Tellabs (Canada)","funders":"University of Sistan and Baluchestan","keywords":"Chemistry; Arrhenius equation; Reaction rate constant; Activation energy; Triphenylphosphine; Kinetic energy; Order of reaction; Rate equation; Physical chemistry; Thermodynamics; Kinetics; Reaction mechanism; Reaction rate; Solvent; Organic chemistry; Catalysis; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004358846,0.0004650548,0.0004478428,0.0002318789,0.000160476,0.0003190645,0.0006919802,0.000447049,0.001483118],"category_scores_gemma":[0.0003871892,0.0003028481,0.0005473906,0.0002244237,0.0002406052,0.0005768322,0.0001656477,0.0004130709,0.0004423525],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000387778,"about_ca_system_score_gemma":0.0003138258,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008006873,"about_ca_topic_score_gemma":0.0006069631,"domain_scores_codex":[0.9997656,0.000035846,0.00001622655,0.00005673487,0.00007314439,0.00005248239],"domain_scores_gemma":[0.9998267,0.000070004,0.00004782196,0.00001053389,0.00002858591,0.000016371],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002803437,0.00005790457,0.0004650554,0.0006002988,0.00003406733,0.0001849797,0.00005455024,0.001729531,0.9909713,0.001144361,0.000115688,0.004361948],"study_design_scores_gemma":[0.00001427304,0.0002746515,0.000831717,0.000006607089,0.00002214988,0.0001455242,0.00001947839,0.007473791,0.9899721,0.0001829415,0.001044344,0.00001233287],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9470624,0.01177564,0.03490466,0.0002967303,0.0001156526,0.0002089221,0.0006109791,0.0002295926,0.004795469],"genre_scores_gemma":[0.9879333,0.002902317,0.005747163,0.0000263042,0.00001079243,0.00007876069,0.0002054506,0.00001353679,0.003082328],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001483118,"threshold_uncertainty_score":0.004961491,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005517861482223738,"score_gpt":0.2096584229508774,"score_spread":0.2041405614686536,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}