{"id":"W2012583975","doi":"10.1021/la0357561","title":"Fluorescence Anisotropy in Studies of Solute Interactions with Covalently Modified Colloidal Silica Nanoparticles","year":2003,"lang":"en","type":"article","venue":"Langmuir","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Triethoxysilane; Rhodamine 6G; Aqueous solution; Cationic polymerization; Chemistry; Adsorption; Anisotropy; Fluorescence; Nanosecond; Pyranine; Nanoparticle; Covalent bond; Surface modification; Materials science; Analytical Chemistry (journal); Polymer chemistry; Nanotechnology; Physical chemistry; Organic chemistry; Membrane; Optics; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003774315,0.0004343905,0.000258127,0.0001631333,0.0002445306,0.0002796865,0.000253029,0.0003312887,0.0007427428],"category_scores_gemma":[0.0006592752,0.0002247213,0.0002983163,0.0001989434,0.0003504342,0.0003056381,0.0002297182,0.0006883495,0.0002701001],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005760929,"about_ca_system_score_gemma":0.0002682055,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002253325,"about_ca_topic_score_gemma":0.001750891,"domain_scores_codex":[0.9997876,0.00004192902,0.00000821761,0.00003720757,0.00007551882,0.00004948127],"domain_scores_gemma":[0.999575,0.0001867013,0.00008154713,0.00003206878,0.00008603168,0.00003876048],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002316558,0.000005608157,0.00005989123,0.00001533888,0.000002772942,0.0000143769,0.00002049353,0.00005923244,0.9994024,0.00006208874,0.000005590913,0.0003291164],"study_design_scores_gemma":[0.000002089075,0.00004331246,0.0003926891,0.000001638684,0.000003906157,0.00002293493,0.000009843516,0.0005422881,0.9987024,0.0000110888,0.0002651313,0.000002592945],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927517,0.0007682485,0.005419795,0.00005071223,0.00001088942,0.00001356099,0.00003775801,0.00006133864,0.0008859583],"genre_scores_gemma":[0.99134,0.0008452457,0.005047304,0.00003637022,0.00001181805,0.00002554396,0.000114627,0.00004012409,0.002538892],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002253325,"threshold_uncertainty_score":0.004480481,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02818889013442742,"score_gpt":0.2797815720722818,"score_spread":0.2515926819378544,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}