{"id":"W2012583975","doi":"10.1021/la0357561","title":"Fluorescence Anisotropy in Studies of Solute Interactions with Covalently Modified Colloidal Silica Nanoparticles","year":2003,"lang":"en","type":"article","venue":"Langmuir","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Triethoxysilane; Rhodamine 6G; Aqueous solution; Cationic polymerization; Chemistry; Adsorption; Anisotropy; Fluorescence; Nanosecond; Pyranine; Nanoparticle; Covalent bond; Surface modification; Materials science; Analytical Chemistry (journal); Polymer chemistry; Nanotechnology; Physical chemistry; Organic chemistry; Membrane; Optics; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004707647,0.0001184613,0.0002198835,0.0000292266,0.00005543376,0.000008822885,0.0001030218,0.00004402708,0.0001411842],"category_scores_gemma":[0.00005322128,0.00009639534,0.00005804112,0.0002360973,0.0001923119,0.00006032424,0.00002201587,0.000118186,0.000003893445],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002868692,"about_ca_system_score_gemma":0.00002300546,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001615211,"about_ca_topic_score_gemma":0.00003347212,"domain_scores_codex":[0.9992447,0.00001491619,0.000213175,0.0001848128,0.0001402186,0.0002021386],"domain_scores_gemma":[0.9995741,0.00007740013,0.00007014933,0.0001729299,0.00005626849,0.00004920451],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009448198,0.0002399808,0.02153746,0.0002466704,0.0001256193,0.00002762046,0.0003901539,0.00004944078,0.9729146,0.003909227,0.0004262903,0.00003841545],"study_design_scores_gemma":[0.0006667045,0.00002601673,0.0009231153,0.0001088625,0.00004485066,0.00001616462,0.00151332,0.0001281702,0.9951055,0.0004652995,0.0008523682,0.0001496382],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919176,0.0002303651,0.00001661054,0.00006896747,0.00001202375,0.00002947758,0.00001983536,0.00003633384,0.007668758],"genre_scores_gemma":[0.9988469,0.0000278974,0.0005405918,0.00001847538,0.00001533948,0.00001643935,0.00000562164,0.000009641149,0.0005191194],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02219085,"threshold_uncertainty_score":0.3930888,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02818889013442742,"score_gpt":0.2797815720722818,"score_spread":0.2515926819378544,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}