{"id":"W2012652172","doi":"10.1021/ma2013755","title":"Monitoring in Real-Time the Degrafting of Covalently Attached Fluorescent Polymer Brushes Grafted to Silica Substrates—Effects of pH and Salt","year":2011,"lang":"en","type":"article","venue":"Macromolecules","topic":"Polymer Surface Interaction Studies","field":"Materials Science","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Université de Montréal","funders":"","keywords":"Fluorophore; Total internal reflection fluorescence microscope; Fluorescence; Chemistry; Covalent bond; Polymer; BODIPY; Aqueous solution; Substrate (aquarium); Fluorescence microscope; Polymer chemistry; Acrylic acid; Buffer solution; Hydrolysis; Photochemistry; Chromatography; Organic chemistry; Copolymer; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002572871,0.0001764624,0.0003341916,0.00009816215,0.00006719051,0.0000229911,0.0002341797,0.0000440845,0.00003355987],"category_scores_gemma":[0.0001304263,0.0001345931,0.00005023334,0.0002289785,0.0001772035,0.00008814888,0.0001809615,0.00007625879,0.00002200091],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002516867,"about_ca_system_score_gemma":0.00002136024,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003468247,"about_ca_topic_score_gemma":0.0001014,"domain_scores_codex":[0.998629,0.0001539228,0.000411272,0.0002760253,0.0002303895,0.0002993817],"domain_scores_gemma":[0.9991463,0.000271254,0.0001793228,0.0002652929,0.00007158063,0.00006618904],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008776937,0.00007242834,0.05401011,0.00006866641,0.00002282178,0.00001280891,0.003680597,0.000001929079,0.9414024,0.00002329987,0.000009860226,0.0006073207],"study_design_scores_gemma":[0.0001942745,0.00007100098,0.193497,0.0001907713,0.00001961552,0.000004179334,0.0003963786,0.000009394613,0.8055015,0.00001500927,0.000001663569,0.00009928495],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997682,0.001464908,0.00001446466,0.00005587602,0.0001889629,0.0002493312,0.00001129809,0.00003864262,0.0002945287],"genre_scores_gemma":[0.9990878,0.00006892319,0.0007211386,0.00001644261,0.00001692611,0.00003097085,4.837009e-7,0.00001858687,0.00003878806],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1394869,"threshold_uncertainty_score":0.5488545,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02413099694166002,"score_gpt":0.2710782059176883,"score_spread":0.2469472089760283,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}