{"id":"W2012894518","doi":"10.1021/ma070372t","title":"Effect of Ionic Binding on the Self-Diffusion of Anionic Dendrimers and Hydrophilic Polymers in Aqueous Systems as Studied by Pulsed Gradient NMR Techniques","year":2007,"lang":"en","type":"article","venue":"Macromolecules","topic":"NMR spectroscopy and applications","field":"Physics and Astronomy","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada","keywords":"Dendrimer; Cationic polymerization; Vinyl alcohol; Diffusion; Polymer chemistry; Aqueous solution; Polymer; Chemistry; Ionic bonding; Polyelectrolyte; Ionic strength; Pulsed field gradient; Self-diffusion; Physical chemistry; Organic chemistry; Molecule; Thermodynamics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003712764,0.0001465644,0.0002244791,0.00009727538,0.0001052173,0.000014386,0.0001298163,0.00003495359,0.00001654197],"category_scores_gemma":[0.000004450706,0.0001053297,0.00005831253,0.0002341839,0.00007996587,0.00001952597,0.00004439832,0.000123071,0.000002744246],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003966581,"about_ca_system_score_gemma":0.00001567995,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007056704,"about_ca_topic_score_gemma":0.00000698977,"domain_scores_codex":[0.9990981,0.00009650396,0.0002582369,0.0001970649,0.0001365963,0.0002135368],"domain_scores_gemma":[0.9994017,0.0001916245,0.0001596602,0.0001945056,0.00001315427,0.00003937781],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009189051,0.0003436187,0.006265047,0.00007237414,0.0001088836,0.000003809608,0.0004006906,0.00001191301,0.9567597,0.02443642,0.00004393278,0.01146176],"study_design_scores_gemma":[0.0004035752,0.0005861574,0.000411904,0.0001219623,0.00004064171,0.000002635709,0.0004005683,0.0002041587,0.9972992,0.0002587568,0.0001432901,0.000127154],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961831,0.0004558708,0.0001309059,0.00005659057,0.00002140635,0.0005766322,0.0000180054,0.00002504296,0.002532442],"genre_scores_gemma":[0.9998029,0.00003237144,0.00002292438,0.000007694452,0.00001819619,0.00005941395,0.00001156296,0.00001444009,0.00003051984],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04053953,"threshold_uncertainty_score":0.4295221,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003703590392687551,"score_gpt":0.2755954090812417,"score_spread":0.2718918186885542,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}