{"id":"W2013076600","doi":"10.1002/ange.200905650","title":"Bridging Binding Modes of Phosphine‐Stabilized Nitrous Oxide to Zn(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>","year":2009,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":70,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Phosphine; Phosphine oxide; Zinc; Chemistry; Stereochemistry; Physics; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008119898,0.0002423534,0.0001635442,0.000108335,0.000171894,0.0001457872,0.0003963439,0.0002277962,0.001882845],"category_scores_gemma":[0.0001405489,0.0001070394,0.00008613632,0.00006860044,0.000198933,0.0001718664,0.0002498247,0.000130879,0.0002202121],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001925171,"about_ca_system_score_gemma":0.0001118988,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001440483,"about_ca_topic_score_gemma":0.0013947,"domain_scores_codex":[0.999963,0.000004280587,0.000001156146,0.000008655058,0.000008397816,0.00001442766],"domain_scores_gemma":[0.9999647,0.00001080495,0.000006592915,0.000003112527,0.000004816566,0.000009986279],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006690075,0.00002571136,0.000219462,0.0001192254,0.000006252265,0.0001285893,0.0001837894,0.0008036455,0.9937465,0.000743536,0.0001442614,0.00320992],"study_design_scores_gemma":[0.00007396971,0.0004350888,0.001411934,0.00001440973,0.00001857432,0.00009882564,0.000111302,0.005165994,0.9903776,0.0003515351,0.001924248,0.00001649858],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981539,0.000139663,0.000551027,0.00001528247,0.000005211798,0.000004591165,0.00001617294,0.00002019606,0.00109393],"genre_scores_gemma":[0.9986535,0.00009315302,0.0004430447,0.00001150439,0.000001981173,0.000005736006,0.00003372598,0.000007345046,0.0007498934],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001882845,"threshold_uncertainty_score":0.00629878,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01371345247473664,"score_gpt":0.2208134891842367,"score_spread":0.2071000367095,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}