{"id":"W2013094535","doi":"10.1002/chin.200917145","title":"ChemInform Abstract: Silver Ion Induced Grob Fragmentation of γ‐Amino Iodides: Highly Stereoselective Synthesis of Polysubstituted Piperidines.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Stereoselectivity; Fragmentation (computing); Combinatorial chemistry; Ion; Stereochemistry; Organic chemistry; Programming language; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003290316,0.0004706797,0.0007393472,0.0001258578,0.00006823114,0.00002682409,0.0005459084,0.0004985179,0.003249039],"category_scores_gemma":[0.001019573,0.0004767377,0.0002666667,0.0004579329,0.000168009,0.0003910257,0.00007330194,0.0003240478,0.00001661547],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003684494,"about_ca_system_score_gemma":0.0002282947,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005646424,"about_ca_topic_score_gemma":0.000001164823,"domain_scores_codex":[0.9972905,3.427152e-7,0.001202892,0.0004132382,0.0006244965,0.0004685468],"domain_scores_gemma":[0.9973083,0.0004420002,0.0009842726,0.0007809445,0.0003062712,0.0001782186],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001237593,0.0001558913,0.00004888504,0.0003960193,0.00008200525,0.000002382566,0.000755842,2.937858e-7,0.7677498,0.00003842869,0.0003039126,0.2303427],"study_design_scores_gemma":[0.0008057983,0.00003735182,0.001497232,0.0003455064,0.0001364949,0.00002754721,0.0009516425,0.0000107753,0.9951402,0.00009049782,0.0005164969,0.0004404534],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6224771,0.00005022136,0.000001433878,0.00004661579,0.00007245546,0.0001135161,0.00004628115,0.00009005689,0.3771023],"genre_scores_gemma":[0.9967672,0.00003552964,0.0005480036,0.00003618636,0.0001590983,0.00002983279,0.00008469685,0.00003707179,0.002302389],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3747999,"threshold_uncertainty_score":0.9997684,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0191057217300377,"score_gpt":0.2671023763070521,"score_spread":0.2479966545770144,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}