{"id":"W2013217737","doi":"10.1021/om010352u","title":"Synthesis, Structural, and Theoretical Analysis of Ru<sub>4</sub>(CO)<sub>12</sub>(μ-PF<sub>2</sub>)(μ<sub>4</sub>-P):  Is the μ<sub>4</sub>-P Atom a Three-Electron or a Five-Electron Donor?","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Boron Compounds in Chemistry","field":"Medicine","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"Centre National de la Recherche Scientifique","keywords":"Chemistry; Crystallography; Atom (system on chip); Ligand (biochemistry); Cluster (spacecraft); Ruthenium; Electron counting; Metal; Molecule; Electron; Stereochemistry; Catalysis; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006905207,0.0001755838,0.0002266475,0.0002447855,0.0002176322,0.0002272344,0.0003512324,0.0002461293,0.002372646],"category_scores_gemma":[0.0001595692,0.0001571612,0.0001200387,0.0002042814,0.0001841765,0.0001498901,0.0001349593,0.0002055771,0.0002958378],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004520954,"about_ca_system_score_gemma":0.0002362635,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001121973,"about_ca_topic_score_gemma":0.001688819,"domain_scores_codex":[0.9999608,0.000004817916,0.000001288013,0.000006155102,0.00001663219,0.00001030297],"domain_scores_gemma":[0.9999741,0.000005007093,0.000005952545,0.0000036242,0.000006118454,0.000005247934],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0006160375,0.0001534549,0.001322127,0.0008745226,0.00003405499,0.0005878703,0.0001599358,0.03529929,0.9169051,0.01114959,0.001970279,0.03092767],"study_design_scores_gemma":[0.00006578349,0.0007851452,0.007363647,0.00002573594,0.00006391528,0.0003711192,0.0002683517,0.1380252,0.8368656,0.003276116,0.01284398,0.00004535246],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9821029,0.0009062049,0.006437102,0.0001567502,0.0000249313,0.00003442002,0.000475006,0.0002027079,0.009659872],"genre_scores_gemma":[0.9924693,0.0003239269,0.004574377,0.00002425192,0.000005154017,0.00002520654,0.0003513761,0.0000335849,0.00219273],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002372646,"threshold_uncertainty_score":0.007937312,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01243450377743275,"score_gpt":0.2588029916029063,"score_spread":0.2463684878254736,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}