{"id":"W2013217737","doi":"10.1021/om010352u","title":"Synthesis, Structural, and Theoretical Analysis of Ru<sub>4</sub>(CO)<sub>12</sub>(μ-PF<sub>2</sub>)(μ<sub>4</sub>-P):  Is the μ<sub>4</sub>-P Atom a Three-Electron or a Five-Electron Donor?","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Boron Compounds in Chemistry","field":"Medicine","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"Centre National de la Recherche Scientifique","keywords":"Chemistry; Crystallography; Atom (system on chip); Ligand (biochemistry); Cluster (spacecraft); Ruthenium; Electron counting; Metal; Molecule; Electron; Stereochemistry; Catalysis; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.002317287,0.003136907,0.004886787,0.001698111,0.001275341,0.0006172213,0.002353063,0.002105655,0.0005251772],"category_scores_gemma":[0.001579716,0.00258,0.002186775,0.006655487,0.003468823,0.0008513918,0.001055455,0.003722796,0.0003047032],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001912185,"about_ca_system_score_gemma":0.001673109,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005396478,"about_ca_topic_score_gemma":0.001075041,"domain_scores_codex":[0.9841577,0.0008514826,0.003529049,0.003946486,0.00339676,0.00411857],"domain_scores_gemma":[0.9873641,0.00309172,0.001988055,0.004710693,0.001102976,0.001742459],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002317234,0.0009033142,0.00505557,0.00068707,0.007072055,0.0003622959,0.0009398879,0.00006416075,0.9496973,0.001774638,0.001909129,0.02921732],"study_design_scores_gemma":[0.003402346,0.00105026,0.01276233,0.000447123,0.01105439,0.001146276,0.0004451713,0.002505299,0.9605477,0.003090765,0.0009244971,0.002623843],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9882281,0.002876122,0.0008679049,0.003112474,0.0004256122,0.002365384,0.0005199127,0.0006911067,0.000913333],"genre_scores_gemma":[0.983291,0.01182364,0.0003383156,0.001443814,0.001225535,0.000399968,0.0006493752,0.0007824948,0.00004586119],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02659348,"threshold_uncertainty_score":0.9992431,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01243450377743275,"score_gpt":0.2588029916029063,"score_spread":0.2463684878254736,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}