{"id":"W2013281946","doi":"10.1002/chin.200428169","title":"Hetero Diels—Alder Reaction of Nitrosoamidines: An Efficient Method for the Synthesis of Functionalized Guanidines.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Diels–Alder reaction; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002931299,0.0001613059,0.000286169,0.00004572308,0.0001010461,0.0000132956,0.0002145232,0.0001206386,0.0003519206],"category_scores_gemma":[0.0004632521,0.0001118399,0.0002707947,0.0001276292,0.00008424907,0.0001024415,0.00002802511,0.00007747669,0.000003879578],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001037885,"about_ca_system_score_gemma":0.00007685101,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000145179,"about_ca_topic_score_gemma":0.000007414537,"domain_scores_codex":[0.9989172,6.890594e-7,0.0004620952,0.0001884732,0.0002562448,0.0001752847],"domain_scores_gemma":[0.9981512,0.0007552232,0.0003305701,0.0005118844,0.000197318,0.00005380532],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003146976,0.000446607,0.0000264605,0.0004571359,0.0002454232,2.874425e-7,0.0004813837,0.0005440327,0.823775,0.001540809,0.0004103425,0.1717578],"study_design_scores_gemma":[0.0004967867,0.00001925062,0.0001781332,0.00007193879,0.0002045937,0.00001158904,0.001503294,0.0003448151,0.9879735,0.0002406153,0.008832361,0.0001231984],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6248588,0.000845632,0.009800702,0.00106228,0.0008738494,0.001095012,0.0004975401,0.0002986383,0.3606676],"genre_scores_gemma":[0.9969783,0.00003692491,0.001152267,0.00002558345,0.0001627073,0.0002356802,0.00004690852,0.00002628295,0.001335313],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3721195,"threshold_uncertainty_score":0.4560699,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02486901760129338,"score_gpt":0.2813583143727634,"score_spread":0.25648929677147,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}