{"id":"W2013303071","doi":"10.1021/ja002360s","title":"Superelectrophilic Tetrakis(carbonyl)palladium(II)- and -platinum(II) Undecafluorodiantimonate(V), [Pd(CO)<sub>4</sub>][Sb<sub>2</sub>F<sub>11</sub>]<sub>2</sub> and [Pt(CO)<sub>4</sub>][Sb<sub>2</sub>F<sub>11</sub>]<sub>2</sub>:  Syntheses, Physical and Spectroscopic Properties, Their Crystal, Molecular, and Extended Structures, and Density Functional Calculations:  An Experimental, Computational, and Comparative Study","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":75,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Isostructural; Crystallography; Palladium; Monoclinic crystal system; Platinum; van der Waals force; Van der Waals radius; Dihedral angle; Crystal structure; Molecule; Hydrogen bond","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004210568,0.0002020002,0.0003001942,0.00008597302,0.0000911057,0.0002013834,0.0003996287,0.0002024338,0.001470843],"category_scores_gemma":[0.000134729,0.0001276965,0.0001097146,0.0001675982,0.0001226228,0.0002217895,0.0001727495,0.0002101835,0.0003163925],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002563674,"about_ca_system_score_gemma":0.0001785171,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001051674,"about_ca_topic_score_gemma":0.002485002,"domain_scores_codex":[0.9999659,0.000003263064,0.000002291058,0.000007852156,0.00001583377,0.000004890029],"domain_scores_gemma":[0.9999682,0.000004963235,0.000009474275,0.000004214485,0.000006730016,0.000006561713],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004659681,0.0001502231,0.002007779,0.0006136644,0.00007017626,0.000216193,0.00005908572,0.008507334,0.9665928,0.003518379,0.0008500323,0.01694837],"study_design_scores_gemma":[0.00009071548,0.0004786648,0.002048637,0.000008358317,0.0000384476,0.0003227179,0.0000750501,0.02315891,0.9643041,0.0003199361,0.009139108,0.00001537301],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895448,0.0005446411,0.006103795,0.00004198339,0.00002326315,0.00002531892,0.0002370349,0.0001675928,0.003311567],"genre_scores_gemma":[0.9903973,0.0005506261,0.006181485,0.00002018897,0.000004960044,0.0000275966,0.0004919742,0.00003266051,0.00229317],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001470843,"threshold_uncertainty_score":0.004920423,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01624210560151051,"score_gpt":0.2411341927447407,"score_spread":0.2248920871432301,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}