{"id":"W2013303071","doi":"10.1021/ja002360s","title":"Superelectrophilic Tetrakis(carbonyl)palladium(II)- and -platinum(II) Undecafluorodiantimonate(V), [Pd(CO)<sub>4</sub>][Sb<sub>2</sub>F<sub>11</sub>]<sub>2</sub> and [Pt(CO)<sub>4</sub>][Sb<sub>2</sub>F<sub>11</sub>]<sub>2</sub>:  Syntheses, Physical and Spectroscopic Properties, Their Crystal, Molecular, and Extended Structures, and Density Functional Calculations:  An Experimental, Computational, and Comparative Study","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":75,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Isostructural; Crystallography; Palladium; Monoclinic crystal system; Platinum; van der Waals force; Van der Waals radius; Dihedral angle; Crystal structure; Molecule; Hydrogen bond","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.001187799,0.003402556,0.004172841,0.0005509395,0.003516531,0.001295285,0.001293664,0.001436088,0.00001501895],"category_scores_gemma":[0.0003625661,0.00292849,0.001326637,0.001925532,0.00519399,0.001571297,0.001578818,0.004656399,0.000009343938],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001921024,"about_ca_system_score_gemma":0.001127623,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001058207,"about_ca_topic_score_gemma":0.0001445048,"domain_scores_codex":[0.9858255,0.001054156,0.003285612,0.003706931,0.003118019,0.003009738],"domain_scores_gemma":[0.990949,0.001336708,0.002789234,0.001672632,0.001117636,0.002134728],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001708754,0.00272365,0.005060388,0.0003831673,0.002732873,0.0002778782,0.004168156,0.0006144365,0.9764159,0.0001277188,0.001378702,0.004408373],"study_design_scores_gemma":[0.006876078,0.001895594,0.01499309,0.0007310408,0.001565622,0.003495516,0.005215191,0.006612092,0.9539102,0.001521851,0.00007087066,0.003112828],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9885516,0.007083411,0.0002105668,0.0008642258,0.0004008356,0.002080234,0.0003805351,0.0003683437,0.00006025474],"genre_scores_gemma":[0.9904174,0.006062494,0.0003187441,0.0008110438,0.001373492,0.0001647552,0.0003420065,0.000505288,0.000004744301],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02250568,"threshold_uncertainty_score":0.9998603,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01624210560151051,"score_gpt":0.2411341927447407,"score_spread":0.2248920871432301,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}