{"id":"W2013433545","doi":"10.3762/bjoc.9.159","title":"Dipolar addition to cyclic vinyl sulfones leading to dual conformation tricycles","year":2013,"lang":"en","type":"article","venue":"Beilstein Journal of Organic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Canadian Institutes of Health Research; Canada Research Chairs; Michael Smith Health Research BC; University of Victoria; Genome British Columbia; University of Notre Dame","keywords":"Chemistry; Nitrogen inversion; Nitrogen; Dipole; NMR spectra database; Spectral line; Combinatorial chemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003553167,0.0003179537,0.0004755463,0.0001543767,0.0001103996,0.0001170302,0.0005147845,0.0002590752,0.01271923],"category_scores_gemma":[0.001040733,0.0003130762,0.0001922508,0.0003464471,0.00004058265,0.0005415155,0.0001088078,0.0004237147,0.0003447635],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004103272,"about_ca_system_score_gemma":0.0001648672,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001401018,"about_ca_topic_score_gemma":0.000002631725,"domain_scores_codex":[0.9977039,0.00002520458,0.001004996,0.000253333,0.0005948244,0.0004177495],"domain_scores_gemma":[0.997835,0.000259138,0.0005967991,0.0004337096,0.0004111071,0.0004642571],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003374711,0.0000718311,0.0002093277,0.0001225671,0.00005643309,0.00001729634,0.0002916526,0.00000413496,0.9681318,0.000003171168,0.008072506,0.02298558],"study_design_scores_gemma":[0.0004533489,0.00005171333,0.000263228,0.0003875813,0.00005337508,0.0002760142,0.001131159,0.000006147238,0.9907984,0.00008292447,0.006150167,0.0003459483],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995194,0.0002523911,0.0009636152,0.0008720406,0.00007749365,0.0001356211,0.00002901016,0.0001444143,0.002331389],"genre_scores_gemma":[0.996724,0.00004511815,0.00159436,0.0001964224,0.0007022372,0.00002775733,0.00002327325,0.00006487046,0.0006219597],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02266664,"threshold_uncertainty_score":0.9999321,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00912959180991669,"score_gpt":0.2312297191453257,"score_spread":0.222100127335409,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}