{"id":"W2013433545","doi":"10.3762/bjoc.9.159","title":"Dipolar addition to cyclic vinyl sulfones leading to dual conformation tricycles","year":2013,"lang":"en","type":"article","venue":"Beilstein Journal of Organic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Canadian Institutes of Health Research; Canada Research Chairs; Michael Smith Health Research BC; University of Victoria; Genome British Columbia; University of Notre Dame","keywords":"Chemistry; Nitrogen inversion; Nitrogen; Dipole; NMR spectra database; Spectral line; Combinatorial chemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001072238,0.0002860157,0.0001597134,0.0002068806,0.00009493191,0.0001948477,0.0002696228,0.0001554118,0.001529835],"category_scores_gemma":[0.0001844517,0.0001053538,0.00009984373,0.0001757925,0.0001637024,0.0001741787,0.0002019541,0.0002552436,0.0002839708],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003004567,"about_ca_system_score_gemma":0.0001734331,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005244089,"about_ca_topic_score_gemma":0.001301127,"domain_scores_codex":[0.9999107,0.00001246988,0.000008474771,0.00002028901,0.0000155916,0.00003246952],"domain_scores_gemma":[0.9999217,0.00001069709,0.00001800546,0.000009485606,0.00001386473,0.00002634127],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001252442,0.00003209311,0.0001198741,0.00009795695,0.000007649377,0.0001723465,0.0001145019,0.0007746643,0.9865411,0.002049207,0.0002105443,0.009754911],"study_design_scores_gemma":[0.0000236265,0.0007236536,0.0006370558,0.00001253614,0.000008784224,0.000138775,0.00003620514,0.001498494,0.9897299,0.0001857305,0.006991537,0.0000138356],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9893765,0.0004949689,0.003049411,0.00005617542,0.00005094777,0.000035204,0.0001983886,0.0001011078,0.006637236],"genre_scores_gemma":[0.993796,0.0003807429,0.002689483,0.00003192963,0.0000068932,0.00002159326,0.0001602577,0.00002233535,0.002890824],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001529835,"threshold_uncertainty_score":0.005117834,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00912959180991669,"score_gpt":0.2312297191453257,"score_spread":0.222100127335409,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}