{"id":"W2013599833","doi":"10.1039/c3ob40213d","title":"Manipulating non-innocent π-spacers: the challenges of using 2,6-disubstituted BODIPY cores within donor–acceptor light-harvesting motifs","year":2013,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"Toronto Metropolitan University","funders":"","keywords":"BODIPY; Chemistry; Photoexcitation; Chromophore; Photochemistry; Acceptor; Conjugated system; Combinatorial chemistry; Fluorescence; Organic chemistry; Excited state; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003661299,0.0003576578,0.0004001736,0.00003560256,0.0002310615,0.0002416628,0.0006802453,0.0001857191,0.001370604],"category_scores_gemma":[0.0002142144,0.0002662469,0.000102668,0.000216517,0.0002156499,0.0003088015,0.0003074003,0.0001377501,0.0001386669],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000981904,"about_ca_system_score_gemma":0.0001266785,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003438026,"about_ca_topic_score_gemma":0.000009787575,"domain_scores_codex":[0.9977584,0.00006885947,0.0006605251,0.0005528181,0.0004373176,0.0005220126],"domain_scores_gemma":[0.9983608,0.00003519609,0.0005369197,0.0007176765,0.0002108924,0.0001384824],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001075322,0.00006750474,0.0006296002,0.0003939251,0.00002535864,0.00001531394,0.0005840069,0.000006080149,0.9981162,0.00002746373,0.00006730204,0.00005646793],"study_design_scores_gemma":[0.0003378648,0.00001697364,0.0005018674,0.0003066203,0.00005178116,0.00004691751,0.001216095,0.0007138636,0.9964305,0.00003978529,0.00001871242,0.0003190429],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951629,0.000581993,0.002645768,0.0003876975,0.0003936888,0.0003761196,0.000009408755,0.00009947424,0.0003429189],"genre_scores_gemma":[0.997729,0.00003242889,0.00176148,0.00006211004,0.0002735619,0.00001856455,0.00001261521,0.00005727306,0.00005294418],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002566092,"threshold_uncertainty_score":0.999979,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02033651506484506,"score_gpt":0.2360554750475447,"score_spread":0.2157189599826997,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}