{"id":"W2013684275","doi":"10.1016/j.saa.2007.11.006","title":"Thermal decomposition studies of the polyhedral oligomeric silsesquioxane, POSSh, and when it is impregnated with the metallocene bis(η5-cyclopentadienyl)zirconium (IV) dichloride or immobilized on silica","year":2007,"lang":"en","type":"article","venue":"Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":5,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University","funders":"Conselho Nacional de Desenvolvimento Científico e Tecnológico; Natural Sciences and Engineering Research Council of Canada; Coordenação de Aperfeiçoamento de Pessoal de Nível Superior; Universidad Nacional de Mar del Plata; Commonwealth Scientific and Industrial Research Organisation","keywords":"Silsesquioxane; Thermogravimetric analysis; Thermal decomposition; Cyclopentadienyl complex; Zirconium; Metallocene; Decomposition; Chemistry; Infrared spectroscopy; Polymer chemistry; Inorganic chemistry; Polymerization; Organic chemistry; Catalysis; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001860424,0.0002853525,0.0001771281,0.0002219177,0.0001766319,0.0001740829,0.0001227653,0.000225431,0.002215729],"category_scores_gemma":[0.000228,0.000145392,0.0002227464,0.0001471575,0.0002878189,0.0002315923,0.00009859147,0.0003308043,0.0003115676],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001948037,"about_ca_system_score_gemma":0.0001240385,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007859291,"about_ca_topic_score_gemma":0.0008318155,"domain_scores_codex":[0.9999062,0.000009721983,0.000005714163,0.00002137887,0.000025049,0.00003191542],"domain_scores_gemma":[0.999873,0.00003734229,0.00002963875,0.00001107277,0.00002791399,0.00002098285],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001028567,0.000008938894,0.0001838809,0.00002061656,0.000004776429,0.00002071844,0.00003864983,0.00005976722,0.9990093,0.00005157792,0.00001520728,0.0004837229],"study_design_scores_gemma":[0.00000356349,0.0001313012,0.00300216,0.000002965378,0.000007006666,0.00004638167,0.00003024336,0.0005511682,0.9959447,0.00001473494,0.0002627011,0.000003086836],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973755,0.0004788775,0.0009314757,0.00002301486,0.000009839544,0.000006443086,0.0001111312,0.00001463966,0.001049048],"genre_scores_gemma":[0.9976879,0.0002530637,0.0004485702,0.0000123824,0.000004382882,0.000007549404,0.0002107252,0.000007165432,0.001368159],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002215729,"threshold_uncertainty_score":0.007412374,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01166456132903961,"score_gpt":0.2813757947359784,"score_spread":0.2697112334069388,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}