{"id":"W2014016741","doi":"10.1139/v01-161","title":"Regioselective upper-rim functionalizations of calix[4]arene by diphenylphosphino groups","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Regioselectivity; Chemistry; Phosphine; Diphenylphosphine; Derivative (finance); Resorcinarene; Calixarene; Transesterification; Medicinal chemistry; Stoichiometry; Tetra; Stereochemistry; Organic chemistry; Molecule; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001675618,0.0005270827,0.000173639,0.000219127,0.0001727896,0.000183752,0.0003127225,0.0001960564,0.002777202],"category_scores_gemma":[0.000198822,0.0001807233,0.000264797,0.0001383014,0.0002116055,0.0003296212,0.0002818502,0.0006566975,0.0005567085],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002015555,"about_ca_system_score_gemma":0.0001277401,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003342104,"about_ca_topic_score_gemma":0.0007618894,"domain_scores_codex":[0.9999007,0.00001335759,0.000008716709,0.00002062274,0.00002812793,0.00002842388],"domain_scores_gemma":[0.9999273,0.00001658747,0.00002340891,0.0000134534,0.000009732736,0.000009484484],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003615863,0.00001349748,0.00002326352,0.00004973003,0.000003048833,0.00004602637,0.00001875547,0.0001293395,0.9970667,0.0003559776,0.0000351805,0.002222251],"study_design_scores_gemma":[0.000006726666,0.00007853002,0.0001946219,0.000001614951,0.000003374104,0.00007762674,0.000005789615,0.0001381856,0.9981056,0.00004061278,0.00134439,0.000002942103],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9739017,0.001361649,0.01251922,0.000139026,0.00004527491,0.0001009583,0.000289443,0.0001631986,0.01147959],"genre_scores_gemma":[0.9786017,0.001451952,0.01233362,0.00009154475,0.00001496073,0.00006773612,0.0004411557,0.00005545686,0.006941839],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002777202,"threshold_uncertainty_score":0.009290636,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00804126350694174,"score_gpt":0.1952472080539405,"score_spread":0.1872059445469988,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}