{"id":"W2014027135","doi":"10.1021/jo0003551","title":"Synthesis of Racemic Brevioxime and Related Model Compounds","year":2000,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Neurobiology and Insect Physiology Research","field":"Neuroscience","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Nitrile; Acetal; Amine gas treating; Oxime; Hydrochloride; Hydrolysis; Thioester; Stereochemistry; Chemical synthesis; Organic chemistry; Combinatorial chemistry; Enzyme; In vitro; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002427111,0.0004306322,0.0004383693,0.0002037628,0.0002951087,0.0002587733,0.0004411652,0.000509509,0.002735974],"category_scores_gemma":[0.0002047736,0.0002053389,0.0002574498,0.0002611559,0.0001693712,0.0003863926,0.0002473069,0.0006261085,0.000948146],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007161464,"about_ca_system_score_gemma":0.0005121625,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001266664,"about_ca_topic_score_gemma":0.001896751,"domain_scores_codex":[0.9998835,0.00001819274,0.000009921006,0.00002461226,0.00002917598,0.00003457931],"domain_scores_gemma":[0.9999092,0.00001025339,0.00002136041,0.00001299788,0.00002191119,0.00002425491],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002655624,0.000110604,0.0001188694,0.0002383816,0.0000170634,0.0001941183,0.0001029817,0.001210702,0.986201,0.002332001,0.0004375113,0.008771184],"study_design_scores_gemma":[0.00006842754,0.001212237,0.0005548469,0.00001779357,0.00002422149,0.0002666904,0.00002326951,0.001003258,0.9745821,0.0002609813,0.02196084,0.00002530897],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9398904,0.01070892,0.02633574,0.0004424374,0.0001638482,0.0007509444,0.003352052,0.000507985,0.01784766],"genre_scores_gemma":[0.9604626,0.006156325,0.01901091,0.0001466389,0.00003615327,0.0003695173,0.001714635,0.00004993698,0.0120533],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002735974,"threshold_uncertainty_score":0.00915271,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01592595243698391,"score_gpt":0.2516837530346879,"score_spread":0.235757800597704,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}