{"id":"W2014104967","doi":"10.1007/s10874-006-9056-4","title":"Laboratory measurements of the 12C/13C kinetic isotope effects in the gas-phase reactions of unsaturated hydrocarbons with Cl atoms at 298 ± 3 K","year":2006,"lang":"en","type":"article","venue":"Journal of Atmospheric Chemistry","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"Environment and Climate Change Canada; York University","funders":"","keywords":"Chemistry; Ethylbenzene; Propene; Cyclopentene; Kinetic isotope effect; Reaction rate constant; Hydrocarbon; Toluene; Analytical Chemistry (journal); Photochemistry; Organic chemistry; Catalysis; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004995927,0.000455728,0.0002627694,0.0003601843,0.0006040058,0.0005900683,0.0006359218,0.0006258621,0.001136164],"category_scores_gemma":[0.0007147474,0.000280859,0.000221458,0.000288508,0.000776979,0.0005199034,0.0002933398,0.0006760332,0.0003700785],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001175872,"about_ca_system_score_gemma":0.0004968065,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006973189,"about_ca_topic_score_gemma":0.005626361,"domain_scores_codex":[0.9997669,0.00002649598,0.00001427446,0.00006229956,0.00007074387,0.0000592049],"domain_scores_gemma":[0.9996154,0.0001382367,0.00005781722,0.00003465678,0.000126719,0.00002723087],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001357222,0.0000960271,0.007086574,0.00006304913,0.00002515541,0.00008129547,0.0001043044,0.0009179392,0.9865447,0.0002984652,0.0002152683,0.003210043],"study_design_scores_gemma":[0.00008894592,0.0002671552,0.009199781,0.000004379759,0.00001766343,0.0000743756,0.00007886223,0.003380295,0.9861412,0.0001006241,0.0006211573,0.0000254863],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966875,0.0002612862,0.001338946,0.00006028259,0.00002191784,0.00001518426,0.0003924173,0.0000663259,0.001156176],"genre_scores_gemma":[0.9989649,0.0001037129,0.0003307358,0.00001620568,0.000006547588,0.000008456861,0.00020501,0.00001252037,0.000351859],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006973189,"threshold_uncertainty_score":0.01386517,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006886892095824959,"score_gpt":0.2013009407140402,"score_spread":0.1944140486182152,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}