{"id":"W2014291646","doi":"10.1021/ic0004636","title":"2-Pyrrolylthiones as Monoanionic Bidentate N,S-Chelators:  Synthesis and Molecular Structure of 2-Pyrrolylthionato Complexes of Nickel(II), Cobalt(III), and Mercury(II)","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Monoclinic crystal system; Denticity; Crystallography; Nickel; Triclinic crystal system; Crystal structure; Octahedron; Chelation; Metal; Cobalt; Ligand (biochemistry); Bond length; Stereochemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00016503,0.0003565109,0.0008739193,0.00006355242,0.0001798081,0.00001882272,0.0001997427,0.0002382997,0.003587928],"category_scores_gemma":[0.0001851447,0.0003032294,0.0001333792,0.0002259125,0.0003798255,0.00009637664,0.0001950149,0.0002647474,0.000006336757],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003605662,"about_ca_system_score_gemma":0.0001252957,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002496683,"about_ca_topic_score_gemma":0.000007675988,"domain_scores_codex":[0.9980479,0.00005207729,0.0006978911,0.0004755393,0.0004311799,0.0002954483],"domain_scores_gemma":[0.9987601,0.0001182797,0.0002514916,0.0005249591,0.0001324844,0.000212664],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000301946,0.0001067967,0.001311611,0.0007838815,0.0002279644,0.000009411871,0.0005320097,0.000002000381,0.9946545,0.00009898508,0.0001092092,0.001861733],"study_design_scores_gemma":[0.0007941328,0.0001607292,0.001977373,0.0003972701,0.0003378567,0.0004382037,0.0004390416,0.00005826098,0.9935029,0.0006535355,0.0009668181,0.0002738629],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899099,0.008143969,0.000002125024,0.0005783663,0.00002791064,0.0002273726,0.00008941193,0.00003875954,0.0009821912],"genre_scores_gemma":[0.9975714,0.001197716,0.0002602885,0.0001608849,0.00004759867,0.000007134185,0.0000236826,0.00004819209,0.0006831007],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007661508,"threshold_uncertainty_score":0.999942,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00889009588861688,"score_gpt":0.2296602423806152,"score_spread":0.2207701464919983,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}