{"id":"W2014293150","doi":"10.1080/10739140600605340","title":"1‐Pyrenemethanol, a Useful Fluorometric Reagent for the Detection and Determination of Carboxylic Acids in Atmospheric Samples","year":2006,"lang":"en","type":"article","venue":"Instrumentation Science & Technology","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Health Canada","keywords":"Derivatization; Reagent; Chemistry; Chromatography; Detection limit; Dichloromethane; High-performance liquid chromatography; Acetonitrile; Solvent; Carboxylic acid; Resolution (logic); Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002263115,0.00009437671,0.0001246659,0.000237236,0.0001524587,0.00002777254,0.0002445862,0.0001154206,0.00002983242],"category_scores_gemma":[0.0001750957,0.00007861696,0.00003634723,0.003136541,0.0008429748,0.0001578364,0.00005266361,0.00008633031,3.726755e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009177649,"about_ca_system_score_gemma":0.0000415808,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001040888,"about_ca_topic_score_gemma":0.00006164581,"domain_scores_codex":[0.9990143,0.000004998239,0.000292925,0.0002765961,0.0002113539,0.0001998289],"domain_scores_gemma":[0.9994162,0.000115061,0.000159027,0.0001975711,0.00009105293,0.00002107662],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001288116,0.00004057934,0.08058456,0.0000414542,0.000004247591,5.1257e-7,0.00004320193,0.00001613705,0.8080386,0.0006563842,6.200049e-7,0.1105608],"study_design_scores_gemma":[0.0004376672,0.00004547726,0.02210025,0.00001562505,0.00002313709,0.0000160086,0.0008442631,0.005844494,0.9662545,0.004159234,0.0001659226,0.00009341173],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9832458,0.0001532837,0.01593901,0.0001182301,0.00002809404,0.0001069001,0.000005385157,0.00004767494,0.0003556495],"genre_scores_gemma":[0.9964228,0.00003757084,0.003406654,0.000008330452,0.00001282505,0.00008345015,0.000003203851,0.000005310268,0.00001982413],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1582159,"threshold_uncertainty_score":0.3205906,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01362291252734766,"score_gpt":0.262079755239266,"score_spread":0.2484568427119184,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}