{"id":"W2014378745","doi":"10.1039/b803097a","title":"Unexpected effect of the fluorine atom on the optimal ligand-to-palladium ratio in the enantioselective Pd-catalyzed allylation reaction of fluorinated enol carbonates","year":2008,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":74,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Palladium; Enantioselective synthesis; Enol; Catalysis; Ligand (biochemistry); Chemistry; Fluorine; Medicinal chemistry; Atom (system on chip); Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006798367,0.0001983044,0.0002689362,0.0000602794,0.0002907304,0.000006854854,0.001500654,0.000224659,0.00003291636],"category_scores_gemma":[0.001042948,0.0001172651,0.0001221125,0.001006961,0.0005398095,0.00004683727,0.0003033316,0.001157739,0.00001201771],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001516592,"about_ca_system_score_gemma":0.0001031779,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007370784,"about_ca_topic_score_gemma":0.00001216751,"domain_scores_codex":[0.9980823,0.0007789994,0.0004838243,0.0002067733,0.0002299321,0.0002181553],"domain_scores_gemma":[0.9943933,0.003820077,0.0002527124,0.001294354,0.0001900513,0.00004951198],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002613254,0.0003054682,0.002052893,0.00001800654,0.00009310002,7.57257e-7,0.001987276,0.0001115591,0.9938902,0.0007975392,0.0003603535,0.000121469],"study_design_scores_gemma":[0.0008551156,0.00006687004,0.004194433,0.00002956271,0.00008977429,0.00001966437,0.0001416958,0.001047791,0.9915279,0.00004716892,0.001869028,0.0001109625],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910185,0.0001784349,0.000005566784,0.005734843,0.000095843,0.0007739919,0.00002280477,0.00003714217,0.002132836],"genre_scores_gemma":[0.9992505,0.0001140622,0.00006225232,0.0001533371,0.00005319289,0.000186569,0.00007665701,0.00001908414,0.00008436717],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008231941,"threshold_uncertainty_score":0.5029866,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06324764137058245,"score_gpt":0.3682637814279211,"score_spread":0.3050161400573387,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}