{"id":"W2014389616","doi":"10.1007/s00216-001-1172-z","title":"Acid digestion of geological and environmental samples using open-vessel focused microwave digestion","year":2002,"lang":"en","type":"article","venue":"Analytical and Bioanalytical Chemistry","topic":"Analytical chemistry methods development","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":false,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Digestion (alchemy); Inductively coupled plasma mass spectrometry; Microwave digestion; Sample preparation; Chemistry; Mass spectrometry; Chromatography; Detection limit","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003005459,0.0004707694,0.0007870607,0.00003951717,0.0001645612,0.0001253004,0.0004023972,0.0005175682,0.003127004],"category_scores_gemma":[0.0005447373,0.0004025022,0.000159561,0.0002087013,0.001338484,0.0001618338,0.0007037719,0.0004942633,0.00000830483],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001378918,"about_ca_system_score_gemma":0.0000300774,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002703354,"about_ca_topic_score_gemma":7.158828e-7,"domain_scores_codex":[0.9971859,0.00003795233,0.0008114992,0.0009290114,0.0004533104,0.0005823321],"domain_scores_gemma":[0.9983377,0.0003907577,0.0001994661,0.0004147422,0.0000527764,0.0006045445],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001470755,0.0006750684,0.03309127,0.000491305,0.0003200694,0.00006538656,0.00004776042,0.000004926417,0.9564726,0.0007852935,0.0000873413,0.007811867],"study_design_scores_gemma":[0.001704619,0.00006829654,0.002659811,0.0002262743,0.0008309346,0.0002431802,0.0003232816,0.08277904,0.9059005,0.002782175,0.001388568,0.00109329],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9835932,0.0007916486,0.004327,0.0008097853,0.00001349941,0.0001045757,0.00009420433,0.00005660166,0.01020944],"genre_scores_gemma":[0.9887559,0.0003651331,0.009156308,0.00007801811,0.0001071064,0.000006486166,0.00007546682,0.00002881276,0.001426786],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08277412,"threshold_uncertainty_score":0.9998427,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05780052484315338,"score_gpt":0.2703029650803644,"score_spread":0.212502440237211,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}