{"id":"W2014496272","doi":"10.1016/s0009-2614(03)00024-1","title":"Interactions of photo-excited zinc phthalocyanine with (hydro)peroxides: triplet vs. singlet state pathways","year":2003,"lang":"en","type":"article","venue":"Chemical Physics Letters","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Photochemistry; Electron paramagnetic resonance; Quenching (fluorescence); Singlet state; Excited state; Singlet oxygen; Triplet state; Radical; Phthalocyanine; Peroxide; Alkoxy group; Zinc; Fluorescence; Nuclear magnetic resonance; Molecule; Organic chemistry; Atomic physics; Oxygen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001660097,0.0003584146,0.0004757541,0.00003758731,0.00007668091,0.00005659947,0.0003531578,0.0000640216,0.0005160376],"category_scores_gemma":[0.00008622877,0.0003141656,0.0001471851,0.0003563856,0.0003620187,0.0002532286,0.00006223733,0.0003132027,0.00006392606],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001148803,"about_ca_system_score_gemma":0.00007288324,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003830638,"about_ca_topic_score_gemma":6.153544e-7,"domain_scores_codex":[0.9980662,0.000059062,0.0004594023,0.0005220917,0.0003963709,0.000496829],"domain_scores_gemma":[0.9986491,0.0001744403,0.0003165438,0.0005584179,0.0001057735,0.0001956968],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000128222,0.0002702306,0.0002587908,0.00009797724,0.00003364482,0.00003093631,0.0002336271,0.0001112629,0.9964209,0.000143244,0.002213171,0.00005801311],"study_design_scores_gemma":[0.0009891806,0.00005104666,0.00003217037,0.0001039354,0.00003427194,0.00006410051,0.00003756371,0.00005835647,0.9962499,0.0004083568,0.00159199,0.0003791366],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.99335,0.00001651824,0.001524369,0.0001785489,0.0001545509,0.0001604392,0.0001194894,0.0001126873,0.004383379],"genre_scores_gemma":[0.9969213,0.000002748473,0.001804086,0.0008775415,0.0001323321,0.00002938752,0.00008565026,0.00005379236,0.00009315562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004290223,"threshold_uncertainty_score":0.999931,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01696619418741587,"score_gpt":0.2239026410166978,"score_spread":0.2069364468292819,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}