{"id":"W2014655943","doi":"10.1021/ic8002004","title":"Photochemical Reactions of <i>fac</i>-[Mn(CO)<sub>3</sub>(phen)imidazole]<sup>+</sup>: Evidence for Long-Lived Radical Species Intermediates","year":2008,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Photochemistry; Photodissociation; Photoisomerization; Absorption spectroscopy; Absorption band; Ligand (biochemistry); Absorption (acoustics); Ultrafast laser spectroscopy; Radical; Electron transfer; Imidazole; Spectroscopy; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004598562,0.0002473248,0.000142451,0.0000590054,0.00009853047,0.0001414828,0.0002392327,0.0001680207,0.001770061],"category_scores_gemma":[0.0001573104,0.00007886946,0.00007189502,0.00009702746,0.000138327,0.0001702812,0.0001216891,0.0002493685,0.0002426739],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004283668,"about_ca_system_score_gemma":0.0001019932,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00115872,"about_ca_topic_score_gemma":0.001295429,"domain_scores_codex":[0.9999378,0.000005093491,0.000002270935,0.00001617683,0.00001725349,0.00002141844],"domain_scores_gemma":[0.9999279,0.00001157949,0.00002984562,0.000005254453,0.00001236803,0.00001308619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001960725,0.00001086642,0.0003762201,0.00005634452,0.00000741023,0.00004162246,0.00002970728,0.00014871,0.9965457,0.0001059166,0.0001105002,0.002371009],"study_design_scores_gemma":[0.000004454957,0.0001113145,0.002284559,0.000002264973,0.000004671774,0.00009366298,0.00001489727,0.0004800301,0.9958753,0.00002131278,0.001104393,0.00000318195],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966837,0.0003609588,0.001014198,0.00003001109,0.000009663278,0.000009830142,0.0001490943,0.00008762921,0.001654938],"genre_scores_gemma":[0.9981654,0.0001182516,0.0005344478,0.00001249226,0.000002008628,0.000005405688,0.0001375656,0.00001473571,0.001009619],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001770061,"threshold_uncertainty_score":0.005921423,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03363366513833062,"score_gpt":0.2616602782474667,"score_spread":0.2280266131091361,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}