{"id":"W2014719430","doi":"10.1139/cjc-2014-0355","title":"Synthesis and characterisation of K<sub>2</sub>[LnTa<sub>3</sub>O<sub>10</sub>]·<i>n</i>H<sub>2</sub>O (Ln = La, Pr, Nd): cation-deficient layered perovskite tantalates for water photolysis","year":2014,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Layered Double Hydroxides Synthesis and Applications","field":"Materials Science","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Thermogravimetric analysis; Chemistry; Non-blocking I/O; Perovskite (structure); Photocatalysis; Crystallography; X-ray crystallography; Rietveld refinement; Crystal structure; Transmission electron microscopy; Powder diffraction; High-resolution transmission electron microscopy; Mineralogy; Nuclear chemistry; Diffraction; Analytical Chemistry (journal); Inorganic chemistry; Physical chemistry; Catalysis; Nanotechnology; Materials science; Organic chemistry; Optics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001204636,0.0002441113,0.0002808092,0.0001656474,0.0001626078,0.000365696,0.0003061491,0.0002831676,0.001001587],"category_scores_gemma":[0.0002888991,0.0002426785,0.000156699,0.0002246589,0.0001702379,0.0002532607,0.0001283497,0.0002477277,0.0004330488],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003068717,"about_ca_system_score_gemma":0.0003489773,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001458049,"about_ca_topic_score_gemma":0.002708016,"domain_scores_codex":[0.999887,0.000007152069,0.00001366458,0.00002195639,0.0000497939,0.00002032366],"domain_scores_gemma":[0.9998344,0.00001731909,0.00004297257,0.00001773955,0.00006798733,0.00001949639],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000153041,0.000003286325,0.00005521667,0.00003185576,0.000001436775,0.00001529181,0.000009197331,0.00004889142,0.9993284,0.00001516158,0.00001430743,0.0004616895],"study_design_scores_gemma":[0.000005134151,0.00004810463,0.0008438932,0.000002025024,0.000006923894,0.00006133507,0.00001559087,0.0002853708,0.9976844,0.000007573708,0.001037232,0.000002486687],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887983,0.0004537837,0.00783189,0.00004259863,0.00002427937,0.00008137915,0.0006754838,0.0001419333,0.001950392],"genre_scores_gemma":[0.980933,0.0006009933,0.01185474,0.00002949426,0.000008715927,0.00007487036,0.0008492011,0.0001150909,0.005533862],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001458049,"threshold_uncertainty_score":0.003350675,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007491259090701598,"score_gpt":0.1916558753102421,"score_spread":0.1841646162195405,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}