{"id":"W2014744513","doi":"10.1007/s10876-012-0470-2","title":"Complete Quenching of the Pd3(dppm)3(CO)2+ Cluster Emission Via Electrostatic Host–Guest Assemblies with Carboxylate-Containing Tetraphenylporphyrins of Ni(II) and Fe(III)","year":2012,"lang":"en","type":"article","venue":"Journal of Cluster Science","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Carboxylate; Chromophore; Chemistry; Nickel; Luminescence; Porphyrin; Quenching (fluorescence); Supramolecular chemistry; Photochemistry; Binding constant; Cluster (spacecraft); Crystallography; Acceptor; Inorganic chemistry; Stereochemistry; Fluorescence; Binding site; Crystal structure; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002289068,0.0002535665,0.0002496582,0.00009584525,0.000177108,0.0003575573,0.0003013607,0.0003872481,0.001200139],"category_scores_gemma":[0.0002284359,0.0001876514,0.0001608038,0.00008258736,0.0003575651,0.0002535018,0.00031597,0.000448381,0.0002805237],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003853352,"about_ca_system_score_gemma":0.0001634996,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004294066,"about_ca_topic_score_gemma":0.0006278083,"domain_scores_codex":[0.9998183,0.00002259321,0.000008003721,0.00004473664,0.00004900658,0.00005750766],"domain_scores_gemma":[0.9998634,0.00003639823,0.00002451808,0.00002465302,0.00001985169,0.00003111869],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008311024,0.000009648788,0.00004797884,0.00002274249,0.000003563963,0.00002074653,0.00002117433,0.00003834688,0.9989414,0.00009396434,0.00003329266,0.0006841276],"study_design_scores_gemma":[0.00000682578,0.00003039018,0.0005875409,0.00000113417,0.000002774471,0.00003003069,0.000003564873,0.0003124599,0.9987859,0.00001159232,0.0002262029,0.000001688085],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956461,0.0002412683,0.002622121,0.00004331354,0.00001423894,0.00001346341,0.00005135489,0.0001111553,0.001256964],"genre_scores_gemma":[0.9979939,0.000059839,0.0006481315,0.00002045774,0.000003910308,0.00001247866,0.00006791436,0.00002912404,0.00116408],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001200139,"threshold_uncertainty_score":0.00401485,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01397429304358114,"score_gpt":0.2583761922359398,"score_spread":0.2444018991923587,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}