{"id":"W2014744513","doi":"10.1007/s10876-012-0470-2","title":"Complete Quenching of the Pd3(dppm)3(CO)2+ Cluster Emission Via Electrostatic Host–Guest Assemblies with Carboxylate-Containing Tetraphenylporphyrins of Ni(II) and Fe(III)","year":2012,"lang":"en","type":"article","venue":"Journal of Cluster Science","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Carboxylate; Chromophore; Chemistry; Nickel; Luminescence; Porphyrin; Quenching (fluorescence); Supramolecular chemistry; Photochemistry; Binding constant; Cluster (spacecraft); Crystallography; Acceptor; Inorganic chemistry; Stereochemistry; Fluorescence; Binding site; Crystal structure; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002405269,0.0002273499,0.0004869976,0.0001745629,0.0003632861,0.00009477174,0.0008471014,0.00006569813,0.00003072577],"category_scores_gemma":[0.0001803109,0.0001354724,0.00009166516,0.0005140052,0.0008963412,0.001138605,0.0002899254,0.0003328783,7.928259e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007959722,"about_ca_system_score_gemma":0.0003495861,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007862706,"about_ca_topic_score_gemma":0.000009097563,"domain_scores_codex":[0.9973161,0.0001070095,0.0007657378,0.0002347913,0.001036088,0.0005403316],"domain_scores_gemma":[0.9975477,0.0001889862,0.001266623,0.0003718112,0.0003580684,0.0002668267],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001438735,0.00006571626,0.04105399,0.00008212751,0.0000115322,0.000002670666,0.002715749,0.00003206866,0.9557336,0.00002713087,0.00008575688,0.00004580435],"study_design_scores_gemma":[0.000993491,0.0004502575,0.03763,0.0004222114,0.00005139131,0.0008165223,0.0004703167,0.0003960979,0.958367,0.00007404842,0.0001264578,0.0002021752],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966943,0.0002751797,0.0008303043,0.0002196613,0.000578164,0.0001341175,0.000009099539,0.000008179221,0.001250991],"genre_scores_gemma":[0.9976692,0.00001473881,0.001904223,0.0001418394,0.0001622954,0.000002006464,4.969231e-7,0.00001430089,0.00009092833],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003423993,"threshold_uncertainty_score":0.5524405,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01397429304358114,"score_gpt":0.2583761922359398,"score_spread":0.2444018991923587,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}