{"id":"W2014747365","doi":"10.1080/10241220902962911","title":"Facile synthesis of novel 2-(4′-N,N-dimethylbenzylidenoimino)-6-substituted-1,3-benzothiazoles and crystal structures of 2-(4′-N,N-dimethylbenzylidenoimino)-6-chloro-1,3-benzothiazole and the co-crystal of 2-amino-6-nitro-1,3-benzothiazole and 4-(N,N-dimethylamino)benzaldehyde","year":2009,"lang":"en","type":"article","venue":"Main Group Chemistry","topic":"Synthesis and biological activity","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Benzothiazole; Chemistry; Nitro; Medicinal chemistry; Stereochemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007978546,0.0002131408,0.0002026483,0.00009172296,0.0001132302,0.0001128123,0.0003914303,0.0002202107,0.0008444203],"category_scores_gemma":[0.00008440022,0.000187847,0.0001534719,0.0001664174,0.0001183276,0.000170202,0.0001437888,0.0003524319,0.0002849042],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002636141,"about_ca_system_score_gemma":0.0002768998,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001123836,"about_ca_topic_score_gemma":0.003881363,"domain_scores_codex":[0.9999385,0.000005364586,0.000004142586,0.000012147,0.00002367901,0.00001610207],"domain_scores_gemma":[0.9999549,0.000004719288,0.00001747865,0.000004091432,0.000008837274,0.000009957043],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001655859,0.0000135871,0.00006423122,0.00003724582,0.000002612866,0.00005344777,0.00001700201,0.000103715,0.9985855,0.0001280841,0.00004451632,0.0009336175],"study_design_scores_gemma":[0.00002549806,0.00022014,0.001977494,0.000003361325,0.00001063588,0.0002190109,0.00002036453,0.001172218,0.991899,0.00003356778,0.004411732,0.000006904941],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826093,0.001774793,0.01023134,0.0001081991,0.00003133663,0.00005865479,0.0003584739,0.0001435322,0.004684356],"genre_scores_gemma":[0.9834046,0.001390521,0.01062514,0.00003334871,0.00001037912,0.00007113197,0.0005695379,0.00002539304,0.003870026],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001123836,"threshold_uncertainty_score":0.002824843,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01330796868762346,"score_gpt":0.2300571330276208,"score_spread":0.2167491643399973,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}