{"id":"W2014756980","doi":"10.1039/c4cp02629b","title":"Introducing asymmetry in tetradentate azadipyrromethene chromophores: a systematic study of the impact on electronic and photophysical properties","year":2014,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds de recherche du Québec – Nature et technologies; Western Canada Research Grid; Compute Canada; University of Manitoba","keywords":"Chromophore; Asymmetry; Photochemistry; Chemistry; Computational chemistry; Nanotechnology; Materials science; Physics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001647225,0.0002725,0.0002521588,0.000149596,0.0001123403,0.0003224875,0.0003575154,0.0002684102,0.001500006],"category_scores_gemma":[0.0004384155,0.0001293028,0.0001369902,0.000286199,0.0001918543,0.0004440646,0.0002036888,0.0005838581,0.0002922099],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003120929,"about_ca_system_score_gemma":0.0001305526,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001726664,"about_ca_topic_score_gemma":0.0003114969,"domain_scores_codex":[0.9998525,0.0000276537,0.0000144338,0.00004765398,0.00003698924,0.00002078097],"domain_scores_gemma":[0.9998068,0.0000579613,0.00005940092,0.00003506594,0.0000250318,0.00001584258],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008324305,0.00004518859,0.0001467766,0.0001360487,0.000008710283,0.00005745641,0.00002260215,0.000319411,0.9943185,0.0006960857,0.00003451248,0.004131514],"study_design_scores_gemma":[0.00001224172,0.0002891066,0.0007005323,0.00000803011,0.00001582359,0.0002187878,0.00001643676,0.001413634,0.9949345,0.00009087742,0.002293205,0.000006842542],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929032,0.001271015,0.003338778,0.00004479882,0.00001436341,0.00004982878,0.0001317793,0.00003601225,0.002210365],"genre_scores_gemma":[0.9916,0.0013131,0.006034725,0.00002400106,0.000005754721,0.00002909762,0.0001126851,0.00002082381,0.0008596769],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001500006,"threshold_uncertainty_score":0.005018055,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008673315808394096,"score_gpt":0.2391600741854644,"score_spread":0.2304867583770703,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}