{"id":"W2014778952","doi":"10.1139/v01-150","title":"Spectroscopic studies of the electrophilic activation of amides with triflic anhydride and pyridine","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":150,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Triflic acid; Pyridinium; Trifluoromethanesulfonate; Pyridine; Electrophile; Organic chemistry; Reagent; Hydrolysis; Medicinal chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000942798,0.000165319,0.0003709173,0.00002572644,0.00006792963,0.000008688443,0.0002782921,0.00008988127,0.0002630619],"category_scores_gemma":[0.000452595,0.0001204775,0.00007494418,0.0002017794,0.0004460734,0.00007452797,0.00001866255,0.0003137753,1.392645e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002346748,"about_ca_system_score_gemma":0.0007563783,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009376993,"about_ca_topic_score_gemma":0.0001270023,"domain_scores_codex":[0.9989716,0.000007303632,0.000434565,0.0001370698,0.0002127828,0.0002366971],"domain_scores_gemma":[0.9985393,0.00009648658,0.0006316322,0.0002984949,0.0002356595,0.0001984251],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004514304,0.00001262937,0.01002283,0.0002762276,0.0001189226,0.00001791153,0.0001926959,0.00003318696,0.9888174,0.000004654032,0.00005208747,0.00040631],"study_design_scores_gemma":[0.0005619652,0.00002579686,0.0006366812,0.0004769675,0.0000566645,0.0004604043,0.0007227918,0.000004509512,0.9960147,0.0003417946,0.0005906509,0.0001070967],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995542,0.001987105,0.00001469589,0.0005075053,0.0000200555,0.00002658484,0.000007813045,0.000003853128,0.001890379],"genre_scores_gemma":[0.998907,0.0002660041,0.00009329196,0.00001721819,0.0001434468,0.000001073716,9.849766e-7,0.00002082945,0.0005501561],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009386149,"threshold_uncertainty_score":0.4912928,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009983462289490567,"score_gpt":0.2232583822341188,"score_spread":0.2132749199446282,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}