{"id":"W2014907576","doi":"10.1021/om010373o","title":"Reactions of Bis(pentafluorophenyl)borane with Cp<sub>2</sub>Ta(CH<sub>2</sub>)CH<sub>3</sub>:  Generation and Trapping of Tantalocene Borataalkene Complexes","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary; University of Alberta; Western University","funders":"","keywords":"Chemistry; Hydride; Methylene; Borane; Ligand (biochemistry); Singlet state; Alkyl; Medicinal chemistry; Crystallography; Stereochemistry; Catalysis; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008243684,0.0003132044,0.0001733989,0.00008161266,0.0001322774,0.0002126275,0.0002746526,0.0002405052,0.00124115],"category_scores_gemma":[0.0001222794,0.000173897,0.0001371802,0.0001043858,0.0001553696,0.0002237673,0.0002187349,0.000324741,0.0003706119],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002660603,"about_ca_system_score_gemma":0.0001599929,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001054,"about_ca_topic_score_gemma":0.001873571,"domain_scores_codex":[0.9999266,0.00001009267,0.000004423438,0.00001400019,0.00001743621,0.00002746508],"domain_scores_gemma":[0.9999571,0.000007797448,0.00001345152,0.00000435692,0.00000577012,0.00001153875],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009842213,0.000009295853,0.00007699345,0.00003234361,0.000008529288,0.00003763981,0.00003329135,0.0001053602,0.9986621,0.0001542792,0.00003731791,0.0007443434],"study_design_scores_gemma":[0.00001447498,0.0001385132,0.0003877147,0.000002211974,0.000006747733,0.00006494874,0.00001363671,0.0003183275,0.997817,0.00002772109,0.001204217,0.000004380733],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934061,0.0006377153,0.003058276,0.00006077023,0.00002847154,0.00003692244,0.00009751054,0.00007628134,0.002598076],"genre_scores_gemma":[0.9947136,0.0003442544,0.001996264,0.00003242786,0.000003973439,0.00001959746,0.0001292983,0.00002368919,0.00273679],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00124115,"threshold_uncertainty_score":0.00415206,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01616969823105491,"score_gpt":0.2172504013043026,"score_spread":0.2010807030732477,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}