{"id":"W2014907576","doi":"10.1021/om010373o","title":"Reactions of Bis(pentafluorophenyl)borane with Cp<sub>2</sub>Ta(CH<sub>2</sub>)CH<sub>3</sub>:  Generation and Trapping of Tantalocene Borataalkene Complexes","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary; University of Alberta; Western University","funders":"","keywords":"Chemistry; Hydride; Methylene; Borane; Ligand (biochemistry); Singlet state; Alkyl; Medicinal chemistry; Crystallography; Stereochemistry; Catalysis; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003278095,0.0009592072,0.001304188,0.0003073141,0.0003991897,0.0001501799,0.0005617132,0.0005985002,0.000549454],"category_scores_gemma":[0.0001454933,0.0009925326,0.0002633064,0.001579577,0.0006944474,0.0006051247,0.0002221683,0.0006785308,0.00003561689],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002799667,"about_ca_system_score_gemma":0.0004254277,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005949525,"about_ca_topic_score_gemma":0.000218801,"domain_scores_codex":[0.9953251,0.00008497822,0.001549773,0.00122161,0.0009264895,0.0008920286],"domain_scores_gemma":[0.9964942,0.0001624931,0.001036826,0.001274843,0.000513347,0.0005183356],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001773532,0.0007762895,0.0029614,0.0007788069,0.0004209956,0.00005474734,0.0002487075,0.00006051107,0.9887961,0.0001066597,0.0003174242,0.005301001],"study_design_scores_gemma":[0.002330149,0.0001674582,0.002517945,0.0002493492,0.0004518347,0.0003264302,0.0004796524,0.0002079309,0.9912282,0.00003854273,0.0009786824,0.001023835],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957131,0.00157518,0.0004145242,0.0003051499,0.0001656188,0.0003489172,0.0004607063,0.0002527217,0.0007640682],"genre_scores_gemma":[0.9913161,0.006378918,0.0004251693,0.0001179946,0.0004868103,0.00003923003,0.0009264607,0.0002563802,0.00005293744],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004803739,"threshold_uncertainty_score":0.9992525,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01616969823105491,"score_gpt":0.2172504013043026,"score_spread":0.2010807030732477,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}