{"id":"W2014955835","doi":"10.1039/c2ob27282b","title":"Cucurbit[7]uril host–guest complexes and [2]pseudorotaxanes with N-methylpiperidinium, N-methylpyrrolidinium, and N-methylmorpholinium cations in aqueous solution","year":2012,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Cucurbituril; Chemistry; Aqueous solution; Cationic polymerization; Electrospray ionization; Host–guest chemistry; Supramolecular chemistry; Microbead (research); Stereochemistry; Molecule; Crystallography; Mass spectrometry; Polymer chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002804165,0.0004839596,0.0003163437,0.0001294212,0.0001525548,0.0003096369,0.0003539385,0.0002702997,0.000817364],"category_scores_gemma":[0.000339404,0.0002446663,0.0001142866,0.0001634569,0.0003386438,0.0003665841,0.0002379513,0.0003271496,0.0002156248],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003850699,"about_ca_system_score_gemma":0.0001682693,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005727005,"about_ca_topic_score_gemma":0.001039666,"domain_scores_codex":[0.999732,0.00007908378,0.00001817382,0.00005531615,0.00006090734,0.00005466784],"domain_scores_gemma":[0.9997744,0.00005272782,0.00008645957,0.0000178407,0.00002764637,0.00004096012],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001560513,0.00001500957,0.00006728691,0.00004849712,0.000006747844,0.00002627964,0.00003083405,0.00007735508,0.9990417,0.00005704154,0.00001722514,0.0004558671],"study_design_scores_gemma":[0.00001240449,0.0001896055,0.0003577086,0.000002380946,0.000006671207,0.00004369099,0.000009845734,0.0003921155,0.998594,0.000005469388,0.0003814825,0.000004690487],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980168,0.000480945,0.000733373,0.00001937968,0.000009239115,0.00001849469,0.0000406881,0.0000577394,0.0006232696],"genre_scores_gemma":[0.9967983,0.0003682303,0.001589012,0.00002577598,0.000007633432,0.00002320158,0.0001505406,0.00002601261,0.001011369],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000817364,"threshold_uncertainty_score":0.002793908,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00852864886403493,"score_gpt":0.2193985820734965,"score_spread":0.2108699332094616,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}