{"id":"W2015006635","doi":"10.1255/ejms.694","title":"Gas-Phase Kinetic Measurements of the Ligation of Ni <sup>+</sup> , Cu <sup>+</sup> , Ni(Pyrrole) <sub>1,2</sub> <sup>+</sup> and Cu(Pyrrole) <sub>1,2</sub> <sup>+</sup> with CO <sub>2</sub> , D <sub>2</sub> O, NH <sub>3</sub> and NO","year":2004,"lang":"en","type":"article","venue":"European Journal of Mass Spectrometry","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Luonnontieteiden ja Tekniikan Tutkimuksen Toimikunta; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Pyrrole; Chemistry; Ligand (biochemistry); Analytical Chemistry (journal); Inorganic chemistry; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow","sts"],"category_scores_codex":[0.003642411,0.004027945,0.004905988,0.002082347,0.001634404,0.0006795246,0.003019979,0.0006469265,0.00007583048],"category_scores_gemma":[0.0007843862,0.003611502,0.001994028,0.004102541,0.002869077,0.002576887,0.001577267,0.005029682,0.0002966812],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001351147,"about_ca_system_score_gemma":0.00101312,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004577381,"about_ca_topic_score_gemma":0.00001367581,"domain_scores_codex":[0.9790739,0.002152355,0.005972661,0.003472094,0.005224852,0.004104158],"domain_scores_gemma":[0.9850044,0.001030637,0.005725377,0.003185861,0.002888291,0.002165468],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002074526,0.002841287,0.00782077,0.0008211111,0.003017402,0.0002845664,0.002894495,0.05178623,0.9079338,0.0004254689,0.002667682,0.0174327],"study_design_scores_gemma":[0.01881062,0.003630779,0.002814939,0.002854257,0.002267672,0.0003672679,0.002783017,0.002760798,0.9550942,0.005014005,0.0003217255,0.003280693],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9814912,0.00227434,0.008043555,0.0008272193,0.000404879,0.00242335,0.0007751408,0.0002987924,0.003461519],"genre_scores_gemma":[0.9907722,0.001660854,0.00247088,0.0005372126,0.003043422,0.000106089,0.0002754794,0.001096339,0.00003755653],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04902544,"threshold_uncertainty_score":0.9998446,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01089737683073353,"score_gpt":0.2224793565950154,"score_spread":0.2115819797642819,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}