{"id":"W2015037542","doi":"10.1016/j.poly.2003.08.013","title":"Trimethylantimony(V) tetraphenyldichalcogenoimidodiphosphinates: crystal structure of Me3Sb[O-PPh2N-PPh2S]2, a compound containing true O-monometallic monoconnective phosphorus ligands with XPNPY skeleton","year":2003,"lang":"en","type":"article","venue":"Polyhedron","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; Consiliului National al Cercetarii Stiintifice din Invatamantul Superior","keywords":"Chemistry; Crystallography; Crystal structure; Trigonal bipyramidal molecular geometry; Molecule; Ligand (biochemistry); Nuclear magnetic resonance spectroscopy; Sulfur; Trigonal pyramidal molecular geometry; Antimony; Stereochemistry; Inorganic chemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004644821,0.00011812,0.0001437012,0.0001264887,0.0002148054,0.0003075222,0.0004922755,0.0001683229,0.001798918],"category_scores_gemma":[0.0000942678,0.0001327949,0.00004581862,0.0002121399,0.000120027,0.0001330339,0.0001170258,0.0002608138,0.0002553035],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003782796,"about_ca_system_score_gemma":0.0003662703,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003500169,"about_ca_topic_score_gemma":0.003877539,"domain_scores_codex":[0.9999555,0.000004100892,0.000002398507,0.00001151165,0.00001695235,0.000009485963],"domain_scores_gemma":[0.9999712,0.000005036383,0.000007938666,0.00000327735,0.000003514132,0.000009148092],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007326662,0.00006683276,0.001034211,0.0002351474,0.00002244603,0.000314744,0.00007409997,0.001294997,0.9830313,0.00286905,0.001600786,0.008723658],"study_design_scores_gemma":[0.0004087768,0.0004774582,0.005320943,0.00001519246,0.00003072119,0.0007019415,0.0001347975,0.006737961,0.9676118,0.0003849688,0.01816073,0.00001472062],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9875658,0.0004585983,0.00113023,0.00008294118,0.00001661097,0.00003289972,0.0009172092,0.0001413601,0.009654471],"genre_scores_gemma":[0.9936795,0.0002373505,0.001983413,0.00001887416,0.000003416012,0.00003294825,0.0008394527,0.00002132901,0.003183603],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003500169,"threshold_uncertainty_score":0.006959558,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008827638043810575,"score_gpt":0.2090757561650799,"score_spread":0.2002481181212694,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}