{"id":"W2015037542","doi":"10.1016/j.poly.2003.08.013","title":"Trimethylantimony(V) tetraphenyldichalcogenoimidodiphosphinates: crystal structure of Me3Sb[O-PPh2N-PPh2S]2, a compound containing true O-monometallic monoconnective phosphorus ligands with XPNPY skeleton","year":2003,"lang":"en","type":"article","venue":"Polyhedron","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; Consiliului National al Cercetarii Stiintifice din Invatamantul Superior","keywords":"Chemistry; Crystallography; Crystal structure; Trigonal bipyramidal molecular geometry; Molecule; Ligand (biochemistry); Nuclear magnetic resonance spectroscopy; Sulfur; Trigonal pyramidal molecular geometry; Antimony; Stereochemistry; Inorganic chemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002310154,0.0006772298,0.001040189,0.0002517622,0.0002469041,0.0001253168,0.000429431,0.0003146754,0.002058768],"category_scores_gemma":[0.0001270771,0.0006005843,0.0002759545,0.0006388756,0.0002249202,0.0003057111,0.00006505113,0.0004086542,0.000008707852],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001991263,"about_ca_system_score_gemma":0.0002129289,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002329298,"about_ca_topic_score_gemma":0.00003540653,"domain_scores_codex":[0.9970266,0.00007198884,0.0008331056,0.0008342484,0.0005256057,0.0007085153],"domain_scores_gemma":[0.997833,0.0002911583,0.0007043856,0.0007418625,0.0001800415,0.0002495333],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004998591,0.0003359946,0.01505345,0.0001871423,0.0006134288,0.00002370222,0.001349886,0.00003696643,0.9773772,0.001943016,0.000009157109,0.002570233],"study_design_scores_gemma":[0.002230204,0.0004060417,0.003597845,0.0001526766,0.0002661867,0.00009456237,0.001529114,0.0001413895,0.9874029,0.0007687841,0.00264119,0.0007690776],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9896047,0.002107371,0.0006323463,0.00004835512,0.0001522673,0.0002954487,0.0001934767,0.000148516,0.006817499],"genre_scores_gemma":[0.9982781,0.0001663706,0.0006745245,0.00004634452,0.000109733,0.00002891453,0.0001629265,0.0001345328,0.0003985765],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0114556,"threshold_uncertainty_score":0.9996446,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008827638043810575,"score_gpt":0.2090757561650799,"score_spread":0.2002481181212694,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}