{"id":"W2015080749","doi":"10.1021/ol0481683","title":"Axial and Equatorial Cyclohexylacyl and Tetrahydropyranyl-2-acyl Radicals. An Experimental and Theoretical Study","year":2004,"lang":"en","type":"article","venue":"Organic Letters","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Institute for Nanotechnology","funders":"Engineering and Physical Sciences Research Council; Western Canada Research Grid","keywords":"Chemistry; Radical; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001034908,0.0002627106,0.000272183,0.00001922856,0.0002445309,0.00009134415,0.0001208332,0.00009561201,0.0002258916],"category_scores_gemma":[0.00002525663,0.0002424465,0.00002576097,0.00005158697,0.0006263335,0.000130714,0.00007999338,0.0002674201,0.000001870036],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006078906,"about_ca_system_score_gemma":0.00002531249,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002937771,"about_ca_topic_score_gemma":0.000004627249,"domain_scores_codex":[0.9987178,0.00002298594,0.0001991215,0.000501329,0.0002077232,0.0003510291],"domain_scores_gemma":[0.999502,0.00004570325,0.00002421,0.0002055921,0.000007665555,0.000214848],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001579485,0.0002789846,0.001273794,0.00002954163,0.00007580927,0.00005039797,0.003108524,1.271467e-7,0.9941862,0.000695643,0.0000216418,0.0001213584],"study_design_scores_gemma":[0.004371712,0.0002541134,0.0003868391,0.00001599291,0.00007277795,0.00009730522,0.001443027,0.000006310379,0.9924931,0.0004631086,0.00005419215,0.0003415477],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982078,0.0003727035,0.00004802416,0.0009172526,0.00007364153,0.0001328058,0.000007041863,0.00008003761,0.0001606993],"genre_scores_gemma":[0.9991243,0.00004045964,0.0000398226,0.000319865,0.0004117823,0.00002275533,0.000005717928,0.00003152415,0.000003700831],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004213764,"threshold_uncertainty_score":0.988668,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005753168541156354,"score_gpt":0.2300177129375056,"score_spread":0.2242645443963493,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}