{"id":"W2015081569","doi":"10.1021/ol047716+","title":"Kinetic and Theoretical Study of 4-<i>e</i><i>xo</i> Ring Closures of Carbamoyl Radicals onto CC and CN Bonds","year":2004,"lang":"en","type":"article","venue":"Organic Letters","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Institute for Nanotechnology","funders":"Western Canada Research Grid","keywords":"Chemistry; Radical; Ring (chemistry); Oxime; Electron paramagnetic resonance; Kinetics; Stereochemistry; Kinetic energy; Medicinal chemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003703536,0.0004970992,0.0004106596,0.0003915842,0.0003583917,0.0003325415,0.000557258,0.0004599745,0.005131615],"category_scores_gemma":[0.001003129,0.0002653489,0.0004584228,0.0001907435,0.0004481788,0.000795907,0.0002239536,0.0006386114,0.0004302627],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000933997,"about_ca_system_score_gemma":0.0003813408,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001846625,"about_ca_topic_score_gemma":0.0009848967,"domain_scores_codex":[0.9999084,0.000011024,0.000002919624,0.0000188494,0.00002618371,0.00003263719],"domain_scores_gemma":[0.9995242,0.0003202725,0.00006641377,0.00002454644,0.00003940274,0.00002512073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006063601,0.0004252324,0.004972079,0.001004213,0.00009135043,0.00100063,0.0004062267,0.7155771,0.1528031,0.1002908,0.001360016,0.0214629],"study_design_scores_gemma":[0.00005333191,0.0001952919,0.001436281,0.00001722726,0.00002093645,0.00009151322,0.0000604764,0.9483284,0.04403046,0.004866587,0.000876228,0.00002324266],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9538306,0.001090211,0.02531414,0.0003289265,0.00004588433,0.0000988929,0.0004054131,0.000110121,0.01877576],"genre_scores_gemma":[0.9952609,0.000330204,0.002223252,0.00002049514,0.000006162643,0.00005587818,0.0001295349,0.00001669553,0.001956826],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005131615,"threshold_uncertainty_score":0.01716691,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00499984978918554,"score_gpt":0.2172491023603698,"score_spread":0.2122492525711842,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}