{"id":"W2015084971","doi":"10.3390/m158","title":"A New Heterocyclization Product of Adhyperforin from Hypericum perforatum (St. John's Wort)","year":2000,"lang":"en","type":"article","venue":"Molecules","topic":"Natural Compound Pharmacology Studies","field":"Agricultural and Biological Sciences","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Hypericum perforatum; Phloroglucinol; Hypericum; Hyperforin; Heteronuclear single quantum coherence spectroscopy; Two-dimensional nuclear magnetic resonance spectroscopy; Hypericin; Chemistry; Stereochemistry; Traditional medicine; Biology; Organic chemistry; Medicine; Pharmacology","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005381505,0.0003652571,0.0001746136,0.0002400514,0.0001672102,0.0001730704,0.0001744497,0.0002451817,0.001653578],"category_scores_gemma":[0.00006646747,0.00006866485,0.0002347555,0.0002163294,0.0001529979,0.0002135452,0.0001735019,0.0002914715,0.0003884096],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001589228,"about_ca_system_score_gemma":0.0001800309,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007740245,"about_ca_topic_score_gemma":0.0008953873,"domain_scores_codex":[0.9999518,0.000008275351,0.000002028055,0.00001440553,0.000007642305,0.00001580365],"domain_scores_gemma":[0.9999576,0.000006763982,0.000008427454,0.000006121177,0.000006580142,0.00001450213],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000643365,0.00001511234,0.0001527072,0.00003659653,0.00000520946,0.0002520608,0.00002136661,0.00004355733,0.9965641,0.00008202516,0.00005428413,0.002708682],"study_design_scores_gemma":[0.00002542666,0.0006507984,0.01014378,0.000008378909,0.00002981366,0.001049584,0.0000388452,0.0001449613,0.9828377,0.0001133286,0.004949607,0.000007911066],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887389,0.002631688,0.003744239,0.0001385044,0.00004597825,0.00005113917,0.0008761619,0.00004322149,0.003730267],"genre_scores_gemma":[0.9889147,0.001344154,0.003165882,0.0001281749,0.00003811413,0.00002645767,0.001456223,0.00001695815,0.004909358],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001653578,"threshold_uncertainty_score":0.005531788,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01266052543123691,"score_gpt":0.2206845699340931,"score_spread":0.2080240445028562,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}