{"id":"W2015113717","doi":"10.1016/j.poly.2009.03.011","title":"Synthesis and characterization of adducts of bis(4,4,6-trimethyl-1,3,2-dioxaphosphorinane-2-thione-2-thiolato)cobalt(II) with nitrogen and phosphorus containing Lewis bases: Crystal structures of [Co(S2)2(2-CH3-NC5H4)] and [Co(S2)2(3-CH3-NC5H4)]","year":2009,"lang":"en","type":"article","venue":"Polyhedron","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Picoline; Adduct; Pyridine; Trigonal bipyramidal molecular geometry; Lewis acids and bases; Triphenylphosphine; Cobalt; Octahedral molecular geometry; Bipyridine; Crystal structure; Coordination geometry; Phenanthroline; Acetonitrile; Crystallography; Medicinal chemistry; Inorganic chemistry; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009060873,0.0001357041,0.0001126367,0.0001284078,0.0001208529,0.0001717971,0.0002226423,0.0001904445,0.001097591],"category_scores_gemma":[0.0002007332,0.0001330291,0.0000490912,0.0001193673,0.0001292955,0.0001148759,0.000132194,0.0001321138,0.0002328384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001608604,"about_ca_system_score_gemma":0.0001776597,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009907066,"about_ca_topic_score_gemma":0.001358409,"domain_scores_codex":[0.999921,0.00001014179,0.000004472748,0.00001875756,0.00003265354,0.00001295905],"domain_scores_gemma":[0.9998753,0.00001343925,0.00003658293,0.0000156791,0.00002452052,0.00003444014],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006075475,0.00001027926,0.0003485857,0.00001603947,0.000002982532,0.00002073617,0.00002183407,0.00006917822,0.9985501,0.00006355443,0.00002159833,0.0008143552],"study_design_scores_gemma":[0.000008388141,0.0001055548,0.001867788,0.000001173993,0.000005842178,0.0001087069,0.000014153,0.0004388957,0.9963966,0.00001437416,0.001036849,0.000001635729],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995607,0.0002197808,0.002773143,0.00002310185,0.000004312721,0.00001775013,0.0001281463,0.00004136098,0.001185543],"genre_scores_gemma":[0.9954025,0.00009890981,0.001998271,0.00001151351,0.000002246282,0.0000130895,0.0003148435,0.00001606895,0.002142633],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001097591,"threshold_uncertainty_score":0.003671825,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02007385937380983,"score_gpt":0.2520128266178073,"score_spread":0.2319389672439975,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}